A zinc(II) quinolinone complex (Et3NH)[Zn(qui)Cl-2]: Synthesis, X-ray structure, spectral properties and in vitro cytotoxicity

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33152622" target="_blank" >RIV/61989592:15310/14:33152622 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0022286013010739" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0022286013010739</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2013.12.050" target="_blank" >10.1016/j.molstruc.2013.12.050</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A zinc(II) quinolinone complex (Et3NH)[Zn(qui)Cl-2]: Synthesis, X-ray structure, spectral properties and in vitro cytotoxicity

Popis výsledku v původním jazyce

A new zinc(II) complex with 2-phenyl-3-hydroxy-4(1H)-quinolinone (Hqui) of the composition (Et3NH)[Zn(qui)Cl-2] was prepared and characterized by elemental analysis, FT IR, 1D and 2D NMR, and fluorescence spectroscopy, mass spectrometry and single crystal X-ray analysis. The molecular structure is composed of the triethylammonium (Et3NH+) cations and tetrahedral [Zn-II(qui)Cl-2](-) complex anions, in which the Zn(II) atoms are bidentate coordinated by one qui ligand through keto (O-K) and phenolate (O-p) oxygen atoms and by two chlorido ligands, thus forming the {O2Cl2} donor set, with Zn-O-K = 1.9860(14) angstrom, Zn-O-p 1.9961(14) angstrom and Zn-Cl = 2.2509(6) angstrom and 2.2266(6) angstrom. The complex cations are aligned into 1D supramolecular chains through the N-H...Cl hydrogen bonding between the amine group of the quinolinone ligand and the chlorido ligand of the adjacent complex anion. The amine group from the Et3NH+ cations provides the N H...O-p hydrogen bond with the phen

Název v anglickém jazyce

A zinc(II) quinolinone complex (Et3NH)[Zn(qui)Cl-2]: Synthesis, X-ray structure, spectral properties and in vitro cytotoxicity

Popis výsledku anglicky

A new zinc(II) complex with 2-phenyl-3-hydroxy-4(1H)-quinolinone (Hqui) of the composition (Et3NH)[Zn(qui)Cl-2] was prepared and characterized by elemental analysis, FT IR, 1D and 2D NMR, and fluorescence spectroscopy, mass spectrometry and single crystal X-ray analysis. The molecular structure is composed of the triethylammonium (Et3NH+) cations and tetrahedral [Zn-II(qui)Cl-2](-) complex anions, in which the Zn(II) atoms are bidentate coordinated by one qui ligand through keto (O-K) and phenolate (O-p) oxygen atoms and by two chlorido ligands, thus forming the {O2Cl2} donor set, with Zn-O-K = 1.9860(14) angstrom, Zn-O-p 1.9961(14) angstrom and Zn-Cl = 2.2509(6) angstrom and 2.2266(6) angstrom. The complex cations are aligned into 1D supramolecular chains through the N-H...Cl hydrogen bonding between the amine group of the quinolinone ligand and the chlorido ligand of the adjacent complex anion. The amine group from the Et3NH+ cations provides the N H...O-p hydrogen bond with the phen

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

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Svazek periodika

1060

Číslo periodika v rámci svazku

FEB

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

7

Strana od-do

42-48

Kód UT WoS článku

000331688000008

EID výsledku v databázi Scopus

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