The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156252" target="_blank" >RIV/61989592:15310/15:33156252 - isvavai.cz</a>

Výsledek na webu

<a href="http://pubs.rsc.org/en/content/articlehtml/2015/dt/c4dt03400g" target="_blank" >http://pubs.rsc.org/en/content/articlehtml/2015/dt/c4dt03400g</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c4dt03400g" target="_blank" >10.1039/c4dt03400g</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes

Popis výsledku v původním jazyce

X-ray crystal structures and magnetic properties of an isostructural series of iron(III) Schiff base complexes with the general formula [Fe(L-5)(NCX)].Solv (where H2L5 = N, N'-bis(2-hydroxy-naphthylidene)-1,6-diamino-4-azahexane, X = S, Solv = tetrahydrofuran, 1a; X = S, Solv = methanol and 0.5 pyrazine, 1b; X = S, Solv = butanone, 1c; Solv = N, N'-dimethylformamide, X = S (1d) or X = Se (1d'); X = S, Solv = dimethyl sulfoxide, 1e) are reported. In the crystals, the individual [Fe(L-5)(NCX)] molecules are connected through weak C-H...O, C-H...pi or C-H...S non-covalent contacts into 2D supramolecular networks, while the guest-solvent (Solv) molecules are trapped in the cavities between two adjacent layers, which are furthermore stabilized by N-H...O hydrogen bonds connecting the Solv oxygen atom with the amine group of the [Fe(L-5)(NCX)] molecule, with the N...O distances varying from 2.921(6) angstrom (in 1d') to 3.295(2) angstrom (in 1a). The magnetic properties of the complexes were

Název v anglickém jazyce

The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes

Popis výsledku anglicky

X-ray crystal structures and magnetic properties of an isostructural series of iron(III) Schiff base complexes with the general formula [Fe(L-5)(NCX)].Solv (where H2L5 = N, N'-bis(2-hydroxy-naphthylidene)-1,6-diamino-4-azahexane, X = S, Solv = tetrahydrofuran, 1a; X = S, Solv = methanol and 0.5 pyrazine, 1b; X = S, Solv = butanone, 1c; Solv = N, N'-dimethylformamide, X = S (1d) or X = Se (1d'); X = S, Solv = dimethyl sulfoxide, 1e) are reported. In the crystals, the individual [Fe(L-5)(NCX)] molecules are connected through weak C-H...O, C-H...pi or C-H...S non-covalent contacts into 2D supramolecular networks, while the guest-solvent (Solv) molecules are trapped in the cavities between two adjacent layers, which are furthermore stabilized by N-H...O hydrogen bonds connecting the Solv oxygen atom with the amine group of the [Fe(L-5)(NCX)] molecule, with the N...O distances varying from 2.921(6) angstrom (in 1d') to 3.295(2) angstrom (in 1a). The magnetic properties of the complexes were

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions (print)

ISSN

1477-9226

e-ISSN

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Svazek periodika

44

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

4474-4484

Kód UT WoS článku

000350543000010

EID výsledku v databázi Scopus

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