Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F16%3A33159714" target="_blank" >RIV/61989592:15310/16:33159714 - isvavai.cz</a>
Výsledek na webu
<a href="http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c6gc00864j" target="_blank" >10.1039/c6gc00864j</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions
Popis výsledku v původním jazyce
The use of magnetic nanoparticles as a solid support material for the development of magnetically retrievable catalytic systems has led to a dramatic expansion of their potential applications as they enable environmentally-friendly and sustainable catalytic processes. These quasi-homogeneous catalysts possess numerous benefits such as ease of isolation and separation from the desired reaction mixtures using an external magnet and excellent recyclability. Consequently, much effort has been directed towards the synthesis of magnetically isolable nano-sized particles by developing methods such as co-precipitation, thermal decomposition, microemulsion, hydrothermal techniques etc. Further, in order to render them suitable for catalytic applications, several protection strategies such as surfactant/polymer, silica and carbon coating of magnetic nanoparticles or embedding them in a matrix/support have been reported in the literature. This review focuses on the substantial progress made in the fabrication of nano structured catalysts with special emphasis on the protection and functionalization of the magnetite nano particles (Fe3O4). Finally, considering the importance of coupling chemistry in the field of organic synthesis, a broad overview of the applications of these magnetite nanoparticle-based catalysts in several types of coupling reactions has been presented. The future of catalysis lies in the rational design and development of novel, highly active and recyclable nanocomposite catalysts which would eventually pave the pathway for the establishment of green and sustainable technologies.
Název v anglickém jazyce
Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions
Popis výsledku anglicky
The use of magnetic nanoparticles as a solid support material for the development of magnetically retrievable catalytic systems has led to a dramatic expansion of their potential applications as they enable environmentally-friendly and sustainable catalytic processes. These quasi-homogeneous catalysts possess numerous benefits such as ease of isolation and separation from the desired reaction mixtures using an external magnet and excellent recyclability. Consequently, much effort has been directed towards the synthesis of magnetically isolable nano-sized particles by developing methods such as co-precipitation, thermal decomposition, microemulsion, hydrothermal techniques etc. Further, in order to render them suitable for catalytic applications, several protection strategies such as surfactant/polymer, silica and carbon coating of magnetic nanoparticles or embedding them in a matrix/support have been reported in the literature. This review focuses on the substantial progress made in the fabrication of nano structured catalysts with special emphasis on the protection and functionalization of the magnetite nano particles (Fe3O4). Finally, considering the importance of coupling chemistry in the field of organic synthesis, a broad overview of the applications of these magnetite nanoparticle-based catalysts in several types of coupling reactions has been presented. The future of catalysis lies in the rational design and development of novel, highly active and recyclable nanocomposite catalysts which would eventually pave the pathway for the establishment of green and sustainable technologies.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2016
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Green Chemistry
ISSN
1463-9262
e-ISSN
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Svazek periodika
18
Číslo periodika v rámci svazku
11
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
26
Strana od-do
3184-3209
Kód UT WoS článku
000378178200002
EID výsledku v databázi Scopus
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