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Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F16%3A33159714" target="_blank" >RIV/61989592:15310/16:33159714 - isvavai.cz</a>

  • Výsledek na webu

    <a href="http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2016/gc/c6gc00864j</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c6gc00864j" target="_blank" >10.1039/c6gc00864j</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions

  • Popis výsledku v původním jazyce

    The use of magnetic nanoparticles as a solid support material for the development of magnetically retrievable catalytic systems has led to a dramatic expansion of their potential applications as they enable environmentally-friendly and sustainable catalytic processes. These quasi-homogeneous catalysts possess numerous benefits such as ease of isolation and separation from the desired reaction mixtures using an external magnet and excellent recyclability. Consequently, much effort has been directed towards the synthesis of magnetically isolable nano-sized particles by developing methods such as co-precipitation, thermal decomposition, microemulsion, hydrothermal techniques etc. Further, in order to render them suitable for catalytic applications, several protection strategies such as surfactant/polymer, silica and carbon coating of magnetic nanoparticles or embedding them in a matrix/support have been reported in the literature. This review focuses on the substantial progress made in the fabrication of nano structured catalysts with special emphasis on the protection and functionalization of the magnetite nano particles (Fe3O4). Finally, considering the importance of coupling chemistry in the field of organic synthesis, a broad overview of the applications of these magnetite nanoparticle-based catalysts in several types of coupling reactions has been presented. The future of catalysis lies in the rational design and development of novel, highly active and recyclable nanocomposite catalysts which would eventually pave the pathway for the establishment of green and sustainable technologies.

  • Název v anglickém jazyce

    Fe3O4 (iron oxide)-supported nanocatalysts: synthesis, characterization and applications in coupling reactions

  • Popis výsledku anglicky

    The use of magnetic nanoparticles as a solid support material for the development of magnetically retrievable catalytic systems has led to a dramatic expansion of their potential applications as they enable environmentally-friendly and sustainable catalytic processes. These quasi-homogeneous catalysts possess numerous benefits such as ease of isolation and separation from the desired reaction mixtures using an external magnet and excellent recyclability. Consequently, much effort has been directed towards the synthesis of magnetically isolable nano-sized particles by developing methods such as co-precipitation, thermal decomposition, microemulsion, hydrothermal techniques etc. Further, in order to render them suitable for catalytic applications, several protection strategies such as surfactant/polymer, silica and carbon coating of magnetic nanoparticles or embedding them in a matrix/support have been reported in the literature. This review focuses on the substantial progress made in the fabrication of nano structured catalysts with special emphasis on the protection and functionalization of the magnetite nano particles (Fe3O4). Finally, considering the importance of coupling chemistry in the field of organic synthesis, a broad overview of the applications of these magnetite nanoparticle-based catalysts in several types of coupling reactions has been presented. The future of catalysis lies in the rational design and development of novel, highly active and recyclable nanocomposite catalysts which would eventually pave the pathway for the establishment of green and sustainable technologies.

Klasifikace

  • Druh

    J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

  • CEP obor

    CA - Anorganická chemie

  • OECD FORD obor

Návaznosti výsledku

  • Projekt

    Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Ostatní

  • Rok uplatnění

    2016

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Green Chemistry

  • ISSN

    1463-9262

  • e-ISSN

  • Svazek periodika

    18

  • Číslo periodika v rámci svazku

    11

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    26

  • Strana od-do

    3184-3209

  • Kód UT WoS článku

    000378178200002

  • EID výsledku v databázi Scopus