Synthesis of [15N4]purine labelled cytokinin glycosides derived from zeatins and topolins with 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F19%3A73596946" target="_blank" >RIV/61989592:15310/19:73596946 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/jlcr.3702" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/jlcr.3702</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/jlcr.3702" target="_blank" >10.1002/jlcr.3702</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of [15N4]purine labelled cytokinin glycosides derived from zeatins and topolins with 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group

Popis výsledku v původním jazyce

Synthesis of [15N4]purine labelled cytokinine glycosides derived from zeatins and topolins containing a 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group is described. These N6-substituted adenine derivatives are intended as internal analytic standards for phytohormone analysis. All labelled compounds were prepared from 6-chloro[15N4]purine (1). The equilibrium reaction of 1 with acetobromo--D-glucose gave isomeric 7-β-D (3) and 9-β-D (4) chloro glucosyl precursors, which were treated with the corresponding amines to get desired labelled cytokinin 7-β-D (6) and 9-β-D (5) glucopyranosides. Cytokinins containing 9-β-D-ribofuranosyl group (8) were obtained by direct enzymatic transglycosylation reaction of cytokinins (7) prepared from 6-chloro[15N4]purine (1).

Název v anglickém jazyce

Synthesis of [15N4]purine labelled cytokinin glycosides derived from zeatins and topolins with 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group

Popis výsledku anglicky

Synthesis of [15N4]purine labelled cytokinine glycosides derived from zeatins and topolins containing a 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group is described. These N6-substituted adenine derivatives are intended as internal analytic standards for phytohormone analysis. All labelled compounds were prepared from 6-chloro[15N4]purine (1). The equilibrium reaction of 1 with acetobromo--D-glucose gave isomeric 7-β-D (3) and 9-β-D (4) chloro glucosyl precursors, which were treated with the corresponding amines to get desired labelled cytokinin 7-β-D (6) and 9-β-D (5) glucopyranosides. Cytokinins containing 9-β-D-ribofuranosyl group (8) were obtained by direct enzymatic transglycosylation reaction of cytokinins (7) prepared from 6-chloro[15N4]purine (1).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

<a href="/cs/project/TE02000058" target="_blank" >TE02000058: Centrum kompetence pro molekulární diagnostiku a personalizovanou medicínu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

JOURNAL OF LABELLED COMPOUNDS &amp; RADIOPHARMACEUTICALS

ISSN

0362-4803

e-ISSN

—

Svazek periodika

62

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

118-125

Kód UT WoS článku

000461827600001

EID výsledku v databázi Scopus

2-s2.0-85060145573