Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73601918" target="_blank" >RIV/61989592:15310/20:73601918 - isvavai.cz</a>
Výsledek na webu
<a href="https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01927e" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01927e</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0gc01927e" target="_blank" >10.1039/d0gc01927e</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins
Popis výsledku v původním jazyce
Epoxides are highly useful intermediates in the production of many chemicals, pharmaceuticals, perfumes, and polymers. In view of the continuing demand for epoxides, it is imperative to develop greener and sustainable reaction protocols. To address these challenges, highly active, selective and efficient heterogeneous catalysts have been designed. Historically, there has been a progressive replacement of hazardous peracids and chlorohydrin-based epoxidation of olefins by metal catalysts deployingtert-butyl hydroperoxide (TBHP), hydrogen peroxide (H2O2) and molecular oxygen (O-2) as oxidants. The main focus of this review is to epitomize the wide scope of supported metal nanocatalysts that have been applied for the epoxidation of olefins. The synthesis, activity and selectivity of the nanocatalytic materials along with a critical appraisal of the performance of the support in the epoxidation of olefins are accentuated.
Název v anglickém jazyce
Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins
Popis výsledku anglicky
Epoxides are highly useful intermediates in the production of many chemicals, pharmaceuticals, perfumes, and polymers. In view of the continuing demand for epoxides, it is imperative to develop greener and sustainable reaction protocols. To address these challenges, highly active, selective and efficient heterogeneous catalysts have been designed. Historically, there has been a progressive replacement of hazardous peracids and chlorohydrin-based epoxidation of olefins by metal catalysts deployingtert-butyl hydroperoxide (TBHP), hydrogen peroxide (H2O2) and molecular oxygen (O-2) as oxidants. The main focus of this review is to epitomize the wide scope of supported metal nanocatalysts that have been applied for the epoxidation of olefins. The synthesis, activity and selectivity of the nanocatalytic materials along with a critical appraisal of the performance of the support in the epoxidation of olefins are accentuated.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
21001 - Nano-materials (production and properties)
Návaznosti výsledku
Projekt
—
Návaznosti
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Ostatní
Rok uplatnění
2020
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
GREEN CHEMISTRY
ISSN
1463-9262
e-ISSN
—
Svazek periodika
22
Číslo periodika v rámci svazku
18
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
35
Strana od-do
5902-5936
Kód UT WoS článku
000571356300002
EID výsledku v databázi Scopus
2-s2.0-85092312324