Deep eutectic solvents: cutting-edge applications in cross-coupling reactions

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73601945" target="_blank" >RIV/61989592:15310/20:73601945 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01494j" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01494j</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d0gc01494j" target="_blank" >10.1039/d0gc01494j</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Deep eutectic solvents: cutting-edge applications in cross-coupling reactions

Popis výsledku v původním jazyce

Deep eutectic solvents (DESs), surmised as &quot;the organic reaction medium of the century&quot;, have reverberated a new symphony throughout the present green millennium. A brief historical account of the DES systems and their physicochemical properties as task-specific and designer solvents for cross-coupling reactions are appraised including the hole theory that explains the underlying mechanistic pathway for this emerging neoteric medium. The insights into cross-coupling reactions and their applications are included, highlighting the significant achievements pertaining to the dual role of DESs as a solvent and catalyst. In addition, popular &quot;name-reactions&quot; for the carbon-carbon and carbon-heteroatom bond formations related to the nature of DESs and the core optimum conditions are included. The review also encompasses the novel approaches to privileged catalytic systems and identify the voids left in cross-coupling reactions where DES systems have not made inroads yet. Finally, the challenges of utilizing the neoteric derivatives of DES for these reactions are expounded.

Název v anglickém jazyce

Deep eutectic solvents: cutting-edge applications in cross-coupling reactions

Popis výsledku anglicky

Deep eutectic solvents (DESs), surmised as &quot;the organic reaction medium of the century&quot;, have reverberated a new symphony throughout the present green millennium. A brief historical account of the DES systems and their physicochemical properties as task-specific and designer solvents for cross-coupling reactions are appraised including the hole theory that explains the underlying mechanistic pathway for this emerging neoteric medium. The insights into cross-coupling reactions and their applications are included, highlighting the significant achievements pertaining to the dual role of DESs as a solvent and catalyst. In addition, popular &quot;name-reactions&quot; for the carbon-carbon and carbon-heteroatom bond formations related to the nature of DESs and the core optimum conditions are included. The review also encompasses the novel approaches to privileged catalytic systems and identify the voids left in cross-coupling reactions where DES systems have not made inroads yet. Finally, the challenges of utilizing the neoteric derivatives of DES for these reactions are expounded.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

GREEN CHEMISTRY

ISSN

1463-9262

e-ISSN

—

Svazek periodika

22

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

25

Strana od-do

3668-3692

Kód UT WoS článku

000544314300001

EID výsledku v databázi Scopus

2-s2.0-85087641338