A new series of Schiff base Ni(II)(4) cubanes: Evaluation of magnetic coupling via carboxylate bridges

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609418" target="_blank" >RIV/61989592:15310/21:73609418 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26620/21:PU138456

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0277538720306744" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0277538720306744</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2020.115017" target="_blank" >10.1016/j.poly.2020.115017</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A new series of Schiff base Ni(II)(4) cubanes: Evaluation of magnetic coupling via carboxylate bridges

Popis výsledku v původním jazyce

The Schiff base ligand H2L has been synthesized by condensation of 2-aminophenol with 3-methyl-1-phenyl-4-formylpyrazol-5-one and reaction between H2L and Ni(OOCR3)(2), R = H in 1, -CH3 in 2, Cl in 3, yielded three new tetranuclear Ni(II) complexes. The complexes have been characterized by elemental analysis, IR- and ES-MS spectroscopy. Their structures as well as structure of ligand were determined by single-crystal X-ray diffraction. Compounds 1-3 possesses tetranuclear cubane-like structures containing [Ni4L4(R3COO)(2)](2) complex anions, which are charge balanced by two triethyl ammonium cations. Furthermore, the crystal structure of the Ni(II) cubane compound containing trichloroacetate bridging ligands, is reported for the first time. Variable temperature magnetic susceptibility measurements revealed interplay between ferromagnetic and antiferromagnetic exchange in the tetranuclear cubanelike compounds 1-3, in which ferromagnetic interactions were enhanced by introducing carboxylate bridging groups. DFT calculations supported the analysis of magnetic data.

Název v anglickém jazyce

A new series of Schiff base Ni(II)(4) cubanes: Evaluation of magnetic coupling via carboxylate bridges

Popis výsledku anglicky

The Schiff base ligand H2L has been synthesized by condensation of 2-aminophenol with 3-methyl-1-phenyl-4-formylpyrazol-5-one and reaction between H2L and Ni(OOCR3)(2), R = H in 1, -CH3 in 2, Cl in 3, yielded three new tetranuclear Ni(II) complexes. The complexes have been characterized by elemental analysis, IR- and ES-MS spectroscopy. Their structures as well as structure of ligand were determined by single-crystal X-ray diffraction. Compounds 1-3 possesses tetranuclear cubane-like structures containing [Ni4L4(R3COO)(2)](2) complex anions, which are charge balanced by two triethyl ammonium cations. Furthermore, the crystal structure of the Ni(II) cubane compound containing trichloroacetate bridging ligands, is reported for the first time. Variable temperature magnetic susceptibility measurements revealed interplay between ferromagnetic and antiferromagnetic exchange in the tetranuclear cubanelike compounds 1-3, in which ferromagnetic interactions were enhanced by introducing carboxylate bridging groups. DFT calculations supported the analysis of magnetic data.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/LO1305" target="_blank" >LO1305: Rozvoj centra pokročilých technologií a materiálů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

POLYHEDRON

ISSN

0277-5387

e-ISSN

—

Svazek periodika

196

Číslo periodika v rámci svazku

MAR

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

"115017-1"-"115017-8"

Kód UT WoS článku

000620839300019

EID výsledku v databázi Scopus

2-s2.0-85099260558