3d-4f magnetic exchange interactions and anisotropy in a series of heterobimetallic vanadium(IV)-lanthanide(III) Schiff base complexes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609447" target="_blank" >RIV/61989592:15310/21:73609447 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT01944A" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT01944A</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d1dt01944a" target="_blank" >10.1039/d1dt01944a</a>

Jazyk výsledku

angličtina

Název v původním jazyce

3d-4f magnetic exchange interactions and anisotropy in a series of heterobimetallic vanadium(IV)-lanthanide(III) Schiff base complexes

Popis výsledku v původním jazyce

A series of heterobimetallic Ln(III)-V-IV compounds [Ln(VO)L(NO3)(3)(H2O)] (Ln = Gd(1), Tb(2), Dy(3), and Er (4)) assembled by a Schiff base ligand (H2L = N,N&apos;-bis(1-hydroxy-2-benzylidene-6-methoxy)-1,7-diamino-4-azaheptane) were prepared and studied with experimental and theoretical methods. The single-crystal X-ray analysis revealed the change of the coordination number from 10 found in 1-3 to 9 confirmed in 4. The DC magnetic data were fit with several Hamiltonians to extract the exchange and anisotropy parameters of complexes 1-4. This investigation of magnetic properties was carried out using both DFT and CASSCF theoretical calculations. It was found out that exchange interactions in 1, 3 and 4 are antiferromagnetic, while 2 has ferromagnetic exchange interactions. Moreover, the AC susceptibility measurements revealed the field-induced slow relaxation of magnetization in complexes 2 and 3 which is complicated by the presence of three relaxation channels. Nevertheless, these compounds belong to the first Tb-III-V-IV and Dy-III-V-IV single-molecule magnets in this class of compounds.

Název v anglickém jazyce

3d-4f magnetic exchange interactions and anisotropy in a series of heterobimetallic vanadium(IV)-lanthanide(III) Schiff base complexes

Popis výsledku anglicky

A series of heterobimetallic Ln(III)-V-IV compounds [Ln(VO)L(NO3)(3)(H2O)] (Ln = Gd(1), Tb(2), Dy(3), and Er (4)) assembled by a Schiff base ligand (H2L = N,N&apos;-bis(1-hydroxy-2-benzylidene-6-methoxy)-1,7-diamino-4-azaheptane) were prepared and studied with experimental and theoretical methods. The single-crystal X-ray analysis revealed the change of the coordination number from 10 found in 1-3 to 9 confirmed in 4. The DC magnetic data were fit with several Hamiltonians to extract the exchange and anisotropy parameters of complexes 1-4. This investigation of magnetic properties was carried out using both DFT and CASSCF theoretical calculations. It was found out that exchange interactions in 1, 3 and 4 are antiferromagnetic, while 2 has ferromagnetic exchange interactions. Moreover, the AC susceptibility measurements revealed the field-induced slow relaxation of magnetization in complexes 2 and 3 which is complicated by the presence of three relaxation channels. Nevertheless, these compounds belong to the first Tb-III-V-IV and Dy-III-V-IV single-molecule magnets in this class of compounds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions

ISSN

1477-9226

e-ISSN

—

Svazek periodika

50

Číslo periodika v rámci svazku

39

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

13883-13893

Kód UT WoS článku

000695962500001

EID výsledku v databázi Scopus

2-s2.0-85117037780