Zinc(II) and copper(II) complexes with N-substituted imines derived from 4-amino-1,2,4-triazole: Synthesis, crystal structure, and biological activity

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F23%3A73622595" target="_blank" >RIV/61989592:15310/23:73622595 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0020169322005710" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0020169322005710</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ica.2022.121359" target="_blank" >10.1016/j.ica.2022.121359</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Zinc(II) and copper(II) complexes with N-substituted imines derived from 4-amino-1,2,4-triazole: Synthesis, crystal structure, and biological activity

Popis výsledku v původním jazyce

Reactions of copper(II) and zinc(II) acetates with polynitrogen Schiff bases, namely 4-(pyridin-2-yl)methyl-eneamino-1,2,4-triazole (L-1), 4-(pyridin-3-yl)methyleneamino-1,2,4-triazole (L-2) and 4-(pyridin-4-yl)methyl-eneamino-1,2,4-triazole (L-3), were studied. The reaction of Zn(OAc)(2)center dot 2H(2)O and L1 gave crystals of trinuclear complex [Zn-3(OAc)(6)(L-1)(2)] (1). A similar reaction of Zn(OAc)(2)center dot 2H(2)O and L-2 resulted in 1D coordination polymer [Zn(OAc)(2)(L-2)]n (2). The reactions of Cu(OAc)(2)center dot H2O with L-2 or L-3 gave crystals of 1D coordination polymer {[Cu-2(OAc)(4)(L2)]center dot 2MeCN}n (3) and binuclear complex [Cu-2(OAc)(2)(L-3)(2)]center dot 2MeCN (4), respectively. The structures of the coordination compounds thus obtained were determined by single-crystal X-ray diffraction analysis. Complexes 1-4 demonstrated better antibacterial and antifungal activities in comparison with free L-1, L-2, and L-3 ligands: the strongest antimicrobial activity was observed against E. coli for 2 and 3, and the highest antifungal activity was found for 1 and 2.

Název v anglickém jazyce

Zinc(II) and copper(II) complexes with N-substituted imines derived from 4-amino-1,2,4-triazole: Synthesis, crystal structure, and biological activity

Popis výsledku anglicky

Reactions of copper(II) and zinc(II) acetates with polynitrogen Schiff bases, namely 4-(pyridin-2-yl)methyl-eneamino-1,2,4-triazole (L-1), 4-(pyridin-3-yl)methyleneamino-1,2,4-triazole (L-2) and 4-(pyridin-4-yl)methyl-eneamino-1,2,4-triazole (L-3), were studied. The reaction of Zn(OAc)(2)center dot 2H(2)O and L1 gave crystals of trinuclear complex [Zn-3(OAc)(6)(L-1)(2)] (1). A similar reaction of Zn(OAc)(2)center dot 2H(2)O and L-2 resulted in 1D coordination polymer [Zn(OAc)(2)(L-2)]n (2). The reactions of Cu(OAc)(2)center dot H2O with L-2 or L-3 gave crystals of 1D coordination polymer {[Cu-2(OAc)(4)(L2)]center dot 2MeCN}n (3) and binuclear complex [Cu-2(OAc)(2)(L-3)(2)]center dot 2MeCN (4), respectively. The structures of the coordination compounds thus obtained were determined by single-crystal X-ray diffraction analysis. Complexes 1-4 demonstrated better antibacterial and antifungal activities in comparison with free L-1, L-2, and L-3 ligands: the strongest antimicrobial activity was observed against E. coli for 2 and 3, and the highest antifungal activity was found for 1 and 2.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

INORGANICA CHIMICA ACTA

ISSN

0020-1693

e-ISSN

1873-3255

Svazek periodika

547

Číslo periodika v rámci svazku

MAR

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

9

Strana od-do

"21359-1"-"121359-9"

Kód UT WoS článku

000923162200001

EID výsledku v databázi Scopus

2-s2.0-85145299645