Nanodiamond Supported Ultra-Small Palladium Nanoparticles as an Efficient Catalyst for Suzuki Cross-Coupling Reactions

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F24%3A73626090" target="_blank" >RIV/61989592:15310/24:73626090 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15640/24:73626090

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/14/1/53" target="_blank" >https://www.mdpi.com/2073-4344/14/1/53</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal14010053" target="_blank" >10.3390/catal14010053</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Nanodiamond Supported Ultra-Small Palladium Nanoparticles as an Efficient Catalyst for Suzuki Cross-Coupling Reactions

Popis výsledku v původním jazyce

A nanocatalyst comprising ultra-small palladium nanoparticles supported on nanodiamonds (ultra-small Pd/rNDs) was fabricated via a reduction of palladium (II) salt on oxidized nanodiamond. The prepared catalyst was characterized using XRD, XPS, ICP-MS, AAS, and TEM/HRTEM techniques, including STEM-EDS chemical mapping, which revealed that the modified material is a combination of reduced nanodiamond decorated with palladium nanoparticles. The as-prepared and well-characterized ultra-small Pd supported on rNDs displayed superb catalytic activity for Suzuki–Miyaura cross-coupling reactions at low temperature without any toxic solvents, to obtain the respective products in good-to-excellent yields (75–98%). The catalyst was easily separated from the reaction solution and was reused four times without loss of catalytic activity or chemical stability.

Název v anglickém jazyce

Nanodiamond Supported Ultra-Small Palladium Nanoparticles as an Efficient Catalyst for Suzuki Cross-Coupling Reactions

Popis výsledku anglicky

A nanocatalyst comprising ultra-small palladium nanoparticles supported on nanodiamonds (ultra-small Pd/rNDs) was fabricated via a reduction of palladium (II) salt on oxidized nanodiamond. The prepared catalyst was characterized using XRD, XPS, ICP-MS, AAS, and TEM/HRTEM techniques, including STEM-EDS chemical mapping, which revealed that the modified material is a combination of reduced nanodiamond decorated with palladium nanoparticles. The as-prepared and well-characterized ultra-small Pd supported on rNDs displayed superb catalytic activity for Suzuki–Miyaura cross-coupling reactions at low temperature without any toxic solvents, to obtain the respective products in good-to-excellent yields (75–98%). The catalyst was easily separated from the reaction solution and was reused four times without loss of catalytic activity or chemical stability.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

—

Svazek periodika

14

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

13

Strana od-do

"53-1"-"53-13"

Kód UT WoS článku

001149479700001

EID výsledku v databázi Scopus

2-s2.0-85183401403