Synthesis and characterization of Cu(II), Co(II) and Ni(II) complexes of trithiocyanuric acid: The structure of {N,N '-bis(3-aminopropyl)-1,3-propane-diamine}-(trithiocyanurato)nickel(II)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15410%2F03%3A00001410" target="_blank" >RIV/61989592:15410/03:00001410 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389030:_____/03:56033095 RIV/61989592:15410/03:00001413

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis and characterization of Cu(II), Co(II) and Ni(II) complexes of trithiocyanuric acid: The structure of {N,N '-bis(3-aminopropyl)-1,3-propane-diamine}-(trithiocyanurato)nickel(II)

Popis výsledku v původním jazyce

Copper, cobalt and nickel complexes with nitrogen donor ligands and trithiocyanurate dianion (ttcH(2-)) have been prepared and characterized by elemental analysis, electronic and EPR (copper complexes) spectra, and magnetic susceptibility measurements over the temperature range 78-291 K. Some of the complexes have also been studied by thermal analysis and by cycle voltammetry. Structures of the complexes have been proposed on the basis of magnetic and spectral properties. Two copper complexes of compositions Cu(bpy)(ttcH) and Cu(phen)(ttcH), where bpy=2,2'-bipyridine, phen=1,10-phenanthroline, are probably polymeric, whereas the copper complex with N,N-bis(3-aminopropyl)ethylenediamine (bapen) of composition [Cu(bapen)ttcH)](.)2H(2)O is mononuclear. Weassume distorted octahedral structures for nickel complexes, A single crystal X-ray analysis of [Ni(bappn)(ttcH)](.)5H(2)O shows that the central nickel atom is coordinated by tetradentate nitrogen ligand N,N'-bis(3-aminopropyl)-1,3-propa

Název v anglickém jazyce

Synthesis and characterization of Cu(II), Co(II) and Ni(II) complexes of trithiocyanuric acid: The structure of {N,N '-bis(3-aminopropyl)-1,3-propane-diamine}-(trithiocyanurato)nickel(II)

Popis výsledku anglicky

Copper, cobalt and nickel complexes with nitrogen donor ligands and trithiocyanurate dianion (ttcH(2-)) have been prepared and characterized by elemental analysis, electronic and EPR (copper complexes) spectra, and magnetic susceptibility measurements over the temperature range 78-291 K. Some of the complexes have also been studied by thermal analysis and by cycle voltammetry. Structures of the complexes have been proposed on the basis of magnetic and spectral properties. Two copper complexes of compositions Cu(bpy)(ttcH) and Cu(phen)(ttcH), where bpy=2,2'-bipyridine, phen=1,10-phenanthroline, are probably polymeric, whereas the copper complex with N,N-bis(3-aminopropyl)ethylenediamine (bapen) of composition [Cu(bapen)ttcH)](.)2H(2)O is mononuclear. Weassume distorted octahedral structures for nickel complexes, A single crystal X-ray analysis of [Ni(bappn)(ttcH)](.)5H(2)O shows that the central nickel atom is coordinated by tetradentate nitrogen ligand N,N'-bis(3-aminopropyl)-1,3-propa

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2003

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

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Svazek periodika

56

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

1-11

Kód UT WoS článku

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EID výsledku v databázi Scopus

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