Transition metal-free C-3 functionalization of quinoxalin-2(1H)-ones: recent advances and sanguine future

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73612300" target="_blank" >RIV/61989592:15640/21:73612300 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2021/NJ/D1NJ03445F" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/NJ/D1NJ03445F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d1nj03445f" target="_blank" >10.1039/d1nj03445f</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Transition metal-free C-3 functionalization of quinoxalin-2(1H)-ones: recent advances and sanguine future

Popis výsledku v původním jazyce

Transition metal-free C-3 functionalization of quinoxalin-2(1H)-ones has recently emerged as a modern sustainable protocol, as C-3 functionalized quinoxalin-2(1H)-ones offer robust applications in the medicinal, pharmaceutical and agriculture industry. In recent times, various sustainable protocols for the construction of C-C, C-N, C-P, C-S, and C-O bonds via the C-H functionalization of quinoxalin-2(1H)-ones were developed. A gradual shift from metal-catalyzed to metal-free methodologies has been observed in last few years, as the latter provide an environmentally benign synthetic route in organic chemistry. The present review offers an extensive discussion on recent advances in transition metal-free C-H functionalization of quinoxalin-2(1H)-ones. The review has been decoratively categorized based on C-C, C-O/C-S and C-N/C-P bond formation using metal-free, visible light and electrochemically catalyzed strategies. In addition, mechanistic features of chemical transformation of quinoxalin-2(1H)-ones have been highlighted.

Název v anglickém jazyce

Transition metal-free C-3 functionalization of quinoxalin-2(1H)-ones: recent advances and sanguine future

Popis výsledku anglicky

Transition metal-free C-3 functionalization of quinoxalin-2(1H)-ones has recently emerged as a modern sustainable protocol, as C-3 functionalized quinoxalin-2(1H)-ones offer robust applications in the medicinal, pharmaceutical and agriculture industry. In recent times, various sustainable protocols for the construction of C-C, C-N, C-P, C-S, and C-O bonds via the C-H functionalization of quinoxalin-2(1H)-ones were developed. A gradual shift from metal-catalyzed to metal-free methodologies has been observed in last few years, as the latter provide an environmentally benign synthetic route in organic chemistry. The present review offers an extensive discussion on recent advances in transition metal-free C-H functionalization of quinoxalin-2(1H)-ones. The review has been decoratively categorized based on C-C, C-O/C-S and C-N/C-P bond formation using metal-free, visible light and electrochemically catalyzed strategies. In addition, mechanistic features of chemical transformation of quinoxalin-2(1H)-ones have been highlighted.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21001 - Nano-materials (production and properties)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

NEW JOURNAL OF CHEMISTRY

ISSN

1144-0546

e-ISSN

—

Svazek periodika

45

Číslo periodika v rámci svazku

45

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

42

Strana od-do

18722-18763

Kód UT WoS článku

000704033500001

EID výsledku v databázi Scopus

2-s2.0-85117577617