Engineering graphitic carbon nitride (g-C3N4) for catalytic reduction of CO2to fuels and chemicals: Strategy and mechanism

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73612344" target="_blank" >RIV/61989592:15640/21:73612344 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2021/GC/D1GC01303C" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/GC/D1GC01303C</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d1gc01303c" target="_blank" >10.1039/d1gc01303c</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Engineering graphitic carbon nitride (g-C3N4) for catalytic reduction of CO2to fuels and chemicals: Strategy and mechanism

Popis výsledku v původním jazyce

The reduction of carbon dioxide to useful fuels/chemicals, such as methane, formic, and methanol, is an innovative way to address looming energy and environmental issues. Graphitic carbon nitride (g-C3N4), as a greener and low-cost catalyst for the electrocatalytic and photocatalytic carbon dioxide reduction reaction (CO2RR) to provide usable fuels, is endowed with numerous appealing attributes, e.g., Earth-abundant resources, facile synthesis, metal-free nature, catalytic properties, and unique thermal-physical-chemical stability. Articles on the use of g-C3N4 for CO2 transformation have increased significantly in the past decade, and it is important to provide timely updates in this emerging and active research area. This review emphasizes the rational structural engineering of g-C3N4, including doping (i.e., metal, non-metal, and molecular) and heterojunction formation (i.e., metal, metal oxide, metal phosphide, metal hydroxide, metal complex, Ag-halides, and carbon materials) for electrocatalytic, photoelectrocatalytic, and photocatalytic CO2RR. Besides, an in-depth deciphering of the CO2RR mechanism from experimental, theoretical, and fundamental concepts is provided, including deliberation on the sources/emission and strategies to avoid/reduce CO2 emission. Lastly, a brief conclusion and outlook on the challenges and future prospects are highlighted to assist further in the rational design of the g-C3N4-based catalyst as a selective and efficient catalyst for the CO2RR.

Název v anglickém jazyce

Engineering graphitic carbon nitride (g-C3N4) for catalytic reduction of CO2to fuels and chemicals: Strategy and mechanism

Popis výsledku anglicky

The reduction of carbon dioxide to useful fuels/chemicals, such as methane, formic, and methanol, is an innovative way to address looming energy and environmental issues. Graphitic carbon nitride (g-C3N4), as a greener and low-cost catalyst for the electrocatalytic and photocatalytic carbon dioxide reduction reaction (CO2RR) to provide usable fuels, is endowed with numerous appealing attributes, e.g., Earth-abundant resources, facile synthesis, metal-free nature, catalytic properties, and unique thermal-physical-chemical stability. Articles on the use of g-C3N4 for CO2 transformation have increased significantly in the past decade, and it is important to provide timely updates in this emerging and active research area. This review emphasizes the rational structural engineering of g-C3N4, including doping (i.e., metal, non-metal, and molecular) and heterojunction formation (i.e., metal, metal oxide, metal phosphide, metal hydroxide, metal complex, Ag-halides, and carbon materials) for electrocatalytic, photoelectrocatalytic, and photocatalytic CO2RR. Besides, an in-depth deciphering of the CO2RR mechanism from experimental, theoretical, and fundamental concepts is provided, including deliberation on the sources/emission and strategies to avoid/reduce CO2 emission. Lastly, a brief conclusion and outlook on the challenges and future prospects are highlighted to assist further in the rational design of the g-C3N4-based catalyst as a selective and efficient catalyst for the CO2RR.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21001 - Nano-materials (production and properties)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

GREEN CHEMISTRY

ISSN

1463-9262

e-ISSN

—

Svazek periodika

23

Číslo periodika v rámci svazku

15

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

35

Strana od-do

5394-5428

Kód UT WoS článku

000674032000001

EID výsledku v databázi Scopus

2-s2.0-85112353264