Electronic band structure of 1D pi-d hybridized narrow-gap metal-organic polymers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F22%3A73618780" target="_blank" >RIV/61989592:15640/22:73618780 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68407700:21340/23:00367524

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2023/NR/D2NR05828F" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2023/NR/D2NR05828F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d2nr05828f" target="_blank" >10.1039/d2nr05828f</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electronic band structure of 1D pi-d hybridized narrow-gap metal-organic polymers

Popis výsledku v původním jazyce

One-dimensional (1D) metal-organic (MO) nanowires are captivating from fundamental and technological perspectives due to their distinctive magnetic and electronic properties. The solvent-free synthesis of such nanomaterials on catalytic surfaces provides a unique approach for fabricating low-dimensional single-layer materials with atomic precision and low amount of defects. A detailed understanding of the electronic structure of MO polymers such as band gap and dispersive bands is critical for their prospective implementation into nanodevices such as spin sensors or field-effect transistors. Here, we have performed the on-surface reaction of quinoidal ligands with single cobalt atoms (Co-QDI) on a vicinal Au(788) surface in ultra-high vacuum. This procedure promotes the growth and uniaxial alignment of Co-QDI MO chains along the surface atomic steps, while permitting the mapping of their electronic properties with space-averaging angle-resolved photoemission spectroscopy. In the direction parallel to the principal chain axis, a well-defined 1D band structure with weakly dispersive and dispersive bands is observed, confirming a pronounced electron delocalization. Low-temperature scanning tunneling microscopy/spectroscopy delves into the atomically precise structure of the nanowires and elucidates their narrow bandgap. These findings are supported with GW0 band structure calculations showing that the observed electronic bands emanate from the efficient hybridization of Co(3d) and molecular orbitals. Our work paves the way towards a systematic search of similar 1D π-d hybridized MO chains with tunable electronic and magnetic properties defined by the transition or rare earth metal atom of choice.

Název v anglickém jazyce

Electronic band structure of 1D pi-d hybridized narrow-gap metal-organic polymers

Popis výsledku anglicky

One-dimensional (1D) metal-organic (MO) nanowires are captivating from fundamental and technological perspectives due to their distinctive magnetic and electronic properties. The solvent-free synthesis of such nanomaterials on catalytic surfaces provides a unique approach for fabricating low-dimensional single-layer materials with atomic precision and low amount of defects. A detailed understanding of the electronic structure of MO polymers such as band gap and dispersive bands is critical for their prospective implementation into nanodevices such as spin sensors or field-effect transistors. Here, we have performed the on-surface reaction of quinoidal ligands with single cobalt atoms (Co-QDI) on a vicinal Au(788) surface in ultra-high vacuum. This procedure promotes the growth and uniaxial alignment of Co-QDI MO chains along the surface atomic steps, while permitting the mapping of their electronic properties with space-averaging angle-resolved photoemission spectroscopy. In the direction parallel to the principal chain axis, a well-defined 1D band structure with weakly dispersive and dispersive bands is observed, confirming a pronounced electron delocalization. Low-temperature scanning tunneling microscopy/spectroscopy delves into the atomically precise structure of the nanowires and elucidates their narrow bandgap. These findings are supported with GW0 band structure calculations showing that the observed electronic bands emanate from the efficient hybridization of Co(3d) and molecular orbitals. Our work paves the way towards a systematic search of similar 1D π-d hybridized MO chains with tunable electronic and magnetic properties defined by the transition or rare earth metal atom of choice.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Nanoscale

ISSN

2040-3364

e-ISSN

2040-3372

Svazek periodika

15

Číslo periodika v rámci svazku

5

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

2285-2291

Kód UT WoS článku

000912023200001

EID výsledku v databázi Scopus

2-s2.0-85146328648