Conducting co-polymer derived N, S co-doped metal-free hierarchical nanoporous carbon for robust electrochemical capacitor

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F23%3A73620433" target="_blank" >RIV/61989592:15640/23:73620433 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2352152X23023265?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352152X23023265?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.est.2023.108928" target="_blank" >10.1016/j.est.2023.108928</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Conducting co-polymer derived N, S co-doped metal-free hierarchical nanoporous carbon for robust electrochemical capacitor

Popis výsledku v původním jazyce

The present investigation reported metal-free hierarchical porous and robust Nitrogen (N), Sulphur (S) co-doped carbon (NS-CoP@C) electrode for supercapacitor application. The NS-CoP@C was synthesized by single-step carbonization and activation of thiourea co-doped aniline-pyrrole co-polymer (CoP). The thiourea acted as a doping as well as activating agent. The data of three different electrode materials PANI-PPy co-polymer (CoP), PANI-PPy co-polymer derived Carbon (CoP@C) and N, S co-doped carbon derived from PANI-PPy co-polymer (NS-CoP@C) are compared in the present report. The electrode materials were initially characterized by various spectroscopic techniques. It is observed that among the three electrode material, NS-CoP@C possess higher specific surface area (SSA), high pore volume and hierarchal porous structure with a better mesopore-tomicropore volume ratio. In a three-electrode system, NS-CoP@C possesses a high specific capacitance of 344.2 F/g @ 0.5A/g. Moreover, NS-CoP@C electrode was used to fabricate an all solid-state (PVA-1 M H2SO4 polymer gel electrolyte) and aqueous (1 M H2SO4 electrolyte) symmetrical supercapacitor devices in the twoelectrode system. This NS-CoP@C electrode was used as both positive and negative electrode material in both types of devices. Among them, the solid-state device operates at a wide potential window of 2 V, as a consequence delivering an implausible energy and power density of 45.25 Wh/kg and 1025.64 W/kg while maintaining a capacity retention of 90.1 % even after 8500 charge-discharge cycles. Hence, the excellent performance of conducting PANI-PPy co-polymer-derived N, S co-doped carbon paved new ground for developing an alternative electrode for futuristic energy storage devices.

Název v anglickém jazyce

Conducting co-polymer derived N, S co-doped metal-free hierarchical nanoporous carbon for robust electrochemical capacitor

Popis výsledku anglicky

The present investigation reported metal-free hierarchical porous and robust Nitrogen (N), Sulphur (S) co-doped carbon (NS-CoP@C) electrode for supercapacitor application. The NS-CoP@C was synthesized by single-step carbonization and activation of thiourea co-doped aniline-pyrrole co-polymer (CoP). The thiourea acted as a doping as well as activating agent. The data of three different electrode materials PANI-PPy co-polymer (CoP), PANI-PPy co-polymer derived Carbon (CoP@C) and N, S co-doped carbon derived from PANI-PPy co-polymer (NS-CoP@C) are compared in the present report. The electrode materials were initially characterized by various spectroscopic techniques. It is observed that among the three electrode material, NS-CoP@C possess higher specific surface area (SSA), high pore volume and hierarchal porous structure with a better mesopore-tomicropore volume ratio. In a three-electrode system, NS-CoP@C possesses a high specific capacitance of 344.2 F/g @ 0.5A/g. Moreover, NS-CoP@C electrode was used to fabricate an all solid-state (PVA-1 M H2SO4 polymer gel electrolyte) and aqueous (1 M H2SO4 electrolyte) symmetrical supercapacitor devices in the twoelectrode system. This NS-CoP@C electrode was used as both positive and negative electrode material in both types of devices. Among them, the solid-state device operates at a wide potential window of 2 V, as a consequence delivering an implausible energy and power density of 45.25 Wh/kg and 1025.64 W/kg while maintaining a capacity retention of 90.1 % even after 8500 charge-discharge cycles. Hence, the excellent performance of conducting PANI-PPy co-polymer-derived N, S co-doped carbon paved new ground for developing an alternative electrode for futuristic energy storage devices.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Energy Storage

ISSN

2352-152X

e-ISSN

—

Svazek periodika

73

Číslo periodika v rámci svazku

December

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

13

Strana od-do

—

Kód UT WoS článku

001078378900001

EID výsledku v databázi Scopus

2-s2.0-85170646829