Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62156489%3A43210%2F15%3A43907653" target="_blank" >RIV/62156489:43210/15:43907653 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/00216305:26620/15:PU113805
Výsledek na webu
<a href="http://www.electrochemsci.org/papers/vol10/100201696.pdf" target="_blank" >http://www.electrochemsci.org/papers/vol10/100201696.pdf</a>
DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy
Popis výsledku v původním jazyce
Synthesis, electrochemistry and spectroscopic techniques for five zinc(II) coordination complexes with a combination of tetradentate amines 1,4-bis(3-aminopropyl) piperazine (bapi), triethylenetetramine (tet) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (mtet) and thiodiacetic (tdaH(2)) or 1,3,5-benzenetricarboxylic acid (btcH(3)) are described. These complexes of general formulas [Zn-2(L)(2)(mu-tda)](ClO4)(2) and [Zn-3(L)(3)(mu-btc)](ClO4)(3), where L = bapi, tet, mtet, have been studied in water solution. Their stability has been studied by electrochemical methods (cyclic voltammetry and differential pulse voltammetry) by using the hanging mercury drop electrode. There were also studied interactions of zinc(II) complexes with UV radiation assessed by fluorescence spectroscopy. It was found out that three complexes (Zn-3(bapi)(3)(mu-btc)](ClO4)(3); Zn-3(tet)(3)(mu-btc)](ClO4)(3); Zn-3(mtet)(3)(mu-btc)](ClO4)(3)), after three minutes of UV irradiation became fluorescently active (l
Název v anglickém jazyce
Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy
Popis výsledku anglicky
Synthesis, electrochemistry and spectroscopic techniques for five zinc(II) coordination complexes with a combination of tetradentate amines 1,4-bis(3-aminopropyl) piperazine (bapi), triethylenetetramine (tet) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (mtet) and thiodiacetic (tdaH(2)) or 1,3,5-benzenetricarboxylic acid (btcH(3)) are described. These complexes of general formulas [Zn-2(L)(2)(mu-tda)](ClO4)(2) and [Zn-3(L)(3)(mu-btc)](ClO4)(3), where L = bapi, tet, mtet, have been studied in water solution. Their stability has been studied by electrochemical methods (cyclic voltammetry and differential pulse voltammetry) by using the hanging mercury drop electrode. There were also studied interactions of zinc(II) complexes with UV radiation assessed by fluorescence spectroscopy. It was found out that three complexes (Zn-3(bapi)(3)(mu-btc)](ClO4)(3); Zn-3(tet)(3)(mu-btc)](ClO4)(3); Zn-3(mtet)(3)(mu-btc)](ClO4)(3)), after three minutes of UV irradiation became fluorescently active (l
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CG - Elektrochemie
OECD FORD obor
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Návaznosti výsledku
Projekt
<a href="/cs/project/EE2.3.20.0148" target="_blank" >EE2.3.20.0148: Mezinárodní spolupráce v oblasti "in vivo" zobrazovacích technik</a><br>
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2015
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
International Journal of Electrochemical Science
ISSN
1452-3981
e-ISSN
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Svazek periodika
10
Číslo periodika v rámci svazku
2
Stát vydavatele periodika
CS - Srbsko a Černá Hora
Počet stran výsledku
12
Strana od-do
1696-1707
Kód UT WoS článku
000348365800052
EID výsledku v databázi Scopus
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