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Diffusive Gradients in Thin-films technique for uranium monitoring along a salinity gradient: A comparative study on the performance of Chelex-100, Dow-PIWBA, Diphonix, and Lewatit FO 36 resin gels in the Scheldt estuary

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62156489%3A43210%2F22%3A43920941" target="_blank" >RIV/62156489:43210/22:43920941 - isvavai.cz</a>

  • Výsledek na webu

    <a href="https://doi.org/10.1016/j.talanta.2021.123168" target="_blank" >https://doi.org/10.1016/j.talanta.2021.123168</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.talanta.2021.123168" target="_blank" >10.1016/j.talanta.2021.123168</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Diffusive Gradients in Thin-films technique for uranium monitoring along a salinity gradient: A comparative study on the performance of Chelex-100, Dow-PIWBA, Diphonix, and Lewatit FO 36 resin gels in the Scheldt estuary

  • Popis výsledku v původním jazyce

    Monitoring of uranium in the environment using the Diffusive Gradients in Thin-films (DGT) technique gains in importance as it can provide unique information about the bioavailability of the element and allows its long-term in-situ measurement. Hence, in this study, four DGT binding phases (Chelex-100, Dow-PIWBA, Diphonix, and Lewatit FO 36 resins) were evaluated for uranium monitoring to assess the robustness of their performance in estuarine and marine environments. These DGTs were deployed along the Scheldt estuary (Belgium and the Netherlands) over four campaigns between 2014 and 2021. The DGT performance (ratio of the DGT-determined vs. dissolved U concentration in grab water sample) varied with the water salinity. The Chelex-100 DGTs generally provided good performance in freshwater (median ratios close to 1.0), but an inverse correlation with the increasing salinity was observed (median ratios 0.7 at the stations with salinity &gt;5). The Lewatit FO 36 DGTs provided good performance in the salinity range 0-18 (median ratios 1.0). However, a strong negative influence was observed at stations with high salinity levels (&gt;18, ratio 0.6) and during the long-term deployment in seawater (ratios &lt;0.5 over deployment periods GREATER-THAN OR EQUAL TO2 days). The Dow-PIWBA and Diphonix DGTs provided overall similar results with excellent performances along the whole salinity gradient (median ratios 1.1 and 1.0, respectively). Nevertheless, the long-term deployment trial in seawater (salinity TILDE OPERATOR+D9127) revealed the robustness of Diphonix DGTs that provided outstanding results even after 28 days of deployment (ratio 1.0). The differences in the performance of tested DGT resins were mostly given by the changes of U speciation along the salinity gradient. The speciation modelling of U showed that calcium uranyl carbonate complexes dominate along the Scheldt estuary (from 97 to 86% seawards) with increasing fraction of UO2(CO3)34MINUS SIGN (from 2 to 14%) towards the mouth.

  • Název v anglickém jazyce

    Diffusive Gradients in Thin-films technique for uranium monitoring along a salinity gradient: A comparative study on the performance of Chelex-100, Dow-PIWBA, Diphonix, and Lewatit FO 36 resin gels in the Scheldt estuary

  • Popis výsledku anglicky

    Monitoring of uranium in the environment using the Diffusive Gradients in Thin-films (DGT) technique gains in importance as it can provide unique information about the bioavailability of the element and allows its long-term in-situ measurement. Hence, in this study, four DGT binding phases (Chelex-100, Dow-PIWBA, Diphonix, and Lewatit FO 36 resins) were evaluated for uranium monitoring to assess the robustness of their performance in estuarine and marine environments. These DGTs were deployed along the Scheldt estuary (Belgium and the Netherlands) over four campaigns between 2014 and 2021. The DGT performance (ratio of the DGT-determined vs. dissolved U concentration in grab water sample) varied with the water salinity. The Chelex-100 DGTs generally provided good performance in freshwater (median ratios close to 1.0), but an inverse correlation with the increasing salinity was observed (median ratios 0.7 at the stations with salinity &gt;5). The Lewatit FO 36 DGTs provided good performance in the salinity range 0-18 (median ratios 1.0). However, a strong negative influence was observed at stations with high salinity levels (&gt;18, ratio 0.6) and during the long-term deployment in seawater (ratios &lt;0.5 over deployment periods GREATER-THAN OR EQUAL TO2 days). The Dow-PIWBA and Diphonix DGTs provided overall similar results with excellent performances along the whole salinity gradient (median ratios 1.1 and 1.0, respectively). Nevertheless, the long-term deployment trial in seawater (salinity TILDE OPERATOR+D9127) revealed the robustness of Diphonix DGTs that provided outstanding results even after 28 days of deployment (ratio 1.0). The differences in the performance of tested DGT resins were mostly given by the changes of U speciation along the salinity gradient. The speciation modelling of U showed that calcium uranyl carbonate complexes dominate along the Scheldt estuary (from 97 to 86% seawards) with increasing fraction of UO2(CO3)34MINUS SIGN (from 2 to 14%) towards the mouth.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10406 - Analytical chemistry

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/EF16_019%2F0000869" target="_blank" >EF16_019/0000869: Udržitelná produkce zdravých ryb v různých akvakulturních systémech - PROFISH</a><br>

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2022

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Talanta

  • ISSN

    0039-9140

  • e-ISSN

    1873-3573

  • Svazek periodika

    240

  • Číslo periodika v rámci svazku

    1 April

  • Stát vydavatele periodika

    NL - Nizozemsko

  • Počet stran výsledku

    10

  • Strana od-do

    123168

  • Kód UT WoS článku

    000759222000009

  • EID výsledku v databázi Scopus

    2-s2.0-85121729361