Comparison of kaolin and kaolinitic claystones as raw materials for preparing metakaolinite-based geopolymers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F19%3AN0000020" target="_blank" >RIV/62243136:_____/19:N0000020 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.irsm.cas.cz/materialy/cs_content/2019_doi/Koutnik_CS_2019_0003.pdf" target="_blank" >http://www.irsm.cas.cz/materialy/cs_content/2019_doi/Koutnik_CS_2019_0003.pdf</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.13168/cs.2019.0003" target="_blank" >10.13168/cs.2019.0003</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Comparison of kaolin and kaolinitic claystones as raw materials for preparing metakaolinite-based geopolymers

Popis výsledku v původním jazyce

One kaolin and two kaolinitic claystones were characterized (XRD, XRF, FTIR, TG, SEM, MIP), dehydrated at 750 °C, finely ground and mixed with an alkali activator in weight ratios of 55:80, 55:75, 60:70, 65:65, 70:60 and 75:55. Geopolymer binders were then prepared by water addition up to the invariable content of 34 wt%. The binders were finally mixed with quartz sand in a weight ratio of 40:60. Differences in the properties between the two types of clay materials, changes in these properties due to dehydration and milling, and the impact of the observed differences on the properties of geopolymer binders (dynamic viscosity, pore size distribution, colour shade) and filled geopolymers (flexural strength, compressive strength, elastic modulus) were investigated. The kaolinitic claystones had a morphology different from the kaolin, characterized by smaller kaolinite plates, significantly lower pore volumes with average pore diameters and a higher impurities content that caused a more intense colour compared to kaolin. The above mentioned differences remained unchanged after thermal and mechanical treatment of the starting clay materials. The geopolymer binders prepared from the calcined and milled kaolinitic claystones were darker in colour and had a significantly lower dynamic viscosity (approximately three times) compared to geopolymer binders prepared from kaolin. Dynamic viscosity decreased with decreasing activator content, while volume and pore size increased. The mechanical properties of all the prepared geopolymers were excellent (compressive strength >50 MPa, bending strength >7.9 MPa and elastic modulus >15 GPa) up to a ratio of metakaolinite component/alkali activator of 1:1.

Název v anglickém jazyce

Comparison of kaolin and kaolinitic claystones as raw materials for preparing metakaolinite-based geopolymers

Popis výsledku anglicky

One kaolin and two kaolinitic claystones were characterized (XRD, XRF, FTIR, TG, SEM, MIP), dehydrated at 750 °C, finely ground and mixed with an alkali activator in weight ratios of 55:80, 55:75, 60:70, 65:65, 70:60 and 75:55. Geopolymer binders were then prepared by water addition up to the invariable content of 34 wt%. The binders were finally mixed with quartz sand in a weight ratio of 40:60. Differences in the properties between the two types of clay materials, changes in these properties due to dehydration and milling, and the impact of the observed differences on the properties of geopolymer binders (dynamic viscosity, pore size distribution, colour shade) and filled geopolymers (flexural strength, compressive strength, elastic modulus) were investigated. The kaolinitic claystones had a morphology different from the kaolin, characterized by smaller kaolinite plates, significantly lower pore volumes with average pore diameters and a higher impurities content that caused a more intense colour compared to kaolin. The above mentioned differences remained unchanged after thermal and mechanical treatment of the starting clay materials. The geopolymer binders prepared from the calcined and milled kaolinitic claystones were darker in colour and had a significantly lower dynamic viscosity (approximately three times) compared to geopolymer binders prepared from kaolin. Dynamic viscosity decreased with decreasing activator content, while volume and pore size increased. The mechanical properties of all the prepared geopolymers were excellent (compressive strength >50 MPa, bending strength >7.9 MPa and elastic modulus >15 GPa) up to a ratio of metakaolinite component/alkali activator of 1:1.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

<a href="/cs/project/LO1606" target="_blank" >LO1606: Rozvoj Centra UniCRE</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Ceramics-Silikáty

ISSN

1804-5847

e-ISSN

—

Svazek periodika

63

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

14

Strana od-do

110-123

Kód UT WoS článku

000462844600012

EID výsledku v databázi Scopus

2-s2.0-85064839776