Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F19%3AN0000022" target="_blank" >RIV/62243136:_____/19:N0000022 - isvavai.cz</a>

Výsledek na webu

<a href="https://link.springer.com/content/pdf/10.1007/s10562-019-02856-x.pdf" target="_blank" >https://link.springer.com/content/pdf/10.1007/s10562-019-02856-x.pdf</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10562-019-02856-x" target="_blank" >10.1007/s10562-019-02856-x</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation

Popis výsledku v původním jazyce

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 C and 300 C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.

Název v anglickém jazyce

Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation

Popis výsledku anglicky

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 C and 300 C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

<a href="/cs/project/LO1606" target="_blank" >LO1606: Rozvoj Centra UniCRE</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysis Letters

ISSN

1011-372X

e-ISSN

—

Svazek periodika

149

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

15

Strana od-do

2453–2467

Kód UT WoS článku

000474386700013

EID výsledku v databázi Scopus

2-s2.0-85068090252