Cobalt Based Catalysts on Alkali-Activated Zeolite foams for N2O decomposition

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F21%3AN0000008" target="_blank" >RIV/62243136:_____/21:N0000008 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/62243136:_____/20:N0000037 RIV/00216275:25310/20:39916849 RIV/61989100:27710/20:10246102

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/10/12/1398" target="_blank" >https://www.mdpi.com/2073-4344/10/12/1398</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal10121398" target="_blank" >10.3390/catal10121398</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Cobalt Based Catalysts on Alkali-Activated Zeolite foams for N2O decomposition

Popis výsledku v původním jazyce

In this work, we studied the effect of alkali-activated zeolite foams modifications on properties and catalytic activity of cobalt phases in the process of catalytic decomposition of N2O. The zeolite foam supports were prepared by alkali activation of natural zeolite followed by acid leaching and ion exchange. The cobalt catalysts were synthesised by a dierent deposition technique (direct ion exchange (DIE) and incipient wetness impregnation (IWI) method of cobalt on zeolite foams. For comparison, catalysts on selected supports were prepared and the properties of all were compared in catalytic tests in the pellet form and as crushed catalysts to determine the effect of internal diusion. The catalysts and supports were in detail characterized by a variety of techniques. The catalyst activity strongly depended on the structure of support and synthesis procedure of a cobalt catalyst. Ion exchange method provided active phase with higher surface areas and sites with better reducibility, both of these factors contributed to higher N2O conversions of more than 80% at 450 °C. A large influence can also be attributed to the presence of alkali metals, in particular, potassium, which resulted in a modification of electronic and acid base properties of the cobalt oxide phase on the catalyst surface. The promotional effect of potassium is better reducibility of cobalt species.

Název v anglickém jazyce

Cobalt Based Catalysts on Alkali-Activated Zeolite foams for N2O decomposition

Popis výsledku anglicky

In this work, we studied the effect of alkali-activated zeolite foams modifications on properties and catalytic activity of cobalt phases in the process of catalytic decomposition of N2O. The zeolite foam supports were prepared by alkali activation of natural zeolite followed by acid leaching and ion exchange. The cobalt catalysts were synthesised by a dierent deposition technique (direct ion exchange (DIE) and incipient wetness impregnation (IWI) method of cobalt on zeolite foams. For comparison, catalysts on selected supports were prepared and the properties of all were compared in catalytic tests in the pellet form and as crushed catalysts to determine the effect of internal diusion. The catalysts and supports were in detail characterized by a variety of techniques. The catalyst activity strongly depended on the structure of support and synthesis procedure of a cobalt catalyst. Ion exchange method provided active phase with higher surface areas and sites with better reducibility, both of these factors contributed to higher N2O conversions of more than 80% at 450 °C. A large influence can also be attributed to the presence of alkali metals, in particular, potassium, which resulted in a modification of electronic and acid base properties of the cobalt oxide phase on the catalyst surface. The promotional effect of potassium is better reducibility of cobalt species.

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

—

OECD FORD obor

20400 - Chemical engineering

Projekt

<a href="/cs/project/LO1606" target="_blank" >LO1606: Rozvoj Centra UniCRE</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

—

Svazek periodika

10

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

21

Strana od-do

1-21

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-85097235985