Oxime functionality in surfactant self-assembly: An overview on combating toxicity of organophosphates

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18450%2F15%3A50003736" target="_blank" >RIV/62690094:18450/15:50003736 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11110/15:10295814 RIV/00179906:_____/15:10295814

Výsledek na webu

<a href="http://www.sciencedirect.com/science/article/pii/S0167732215300209" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0167732215300209</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molliq.2015.04.010" target="_blank" >10.1016/j.molliq.2015.04.010</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Oxime functionality in surfactant self-assembly: An overview on combating toxicity of organophosphates

Popis výsledku v původním jazyce

There is an immediate need to develop new strategies for detoxification and decontamination of organophosphorus-containing nerve agents and pesticides. Oximes have witnessed increased scientific interest because of their various applications ranging from acetylcholinesterase reactivators, independent alpha nucleophiles to functionalized nano-aggregates against organophosphate toxicity. The role of oximes as supemucleophilic systems in detoxification reactions is an important research theme and substantial efforts have been made in this report to address this fact. The results have been rationalized in terms of micellar kinetic studies in relation to the oxime structure. The reactivity of oximate ions in cationic micelles, as functionalized aggregates, as reactive polymers and metallomicelles has been well reviewed. Amidoximes emerging as versatile tool in detoxification chemistry has been discussed marginally in the present report. This article motivates similar kinds of studies from different viewpoints. Such studies can be extended to other micellar systems with versatile hydrophobic and hydrophilic properties.

Název v anglickém jazyce

Oxime functionality in surfactant self-assembly: An overview on combating toxicity of organophosphates

Popis výsledku anglicky

There is an immediate need to develop new strategies for detoxification and decontamination of organophosphorus-containing nerve agents and pesticides. Oximes have witnessed increased scientific interest because of their various applications ranging from acetylcholinesterase reactivators, independent alpha nucleophiles to functionalized nano-aggregates against organophosphate toxicity. The role of oximes as supemucleophilic systems in detoxification reactions is an important research theme and substantial efforts have been made in this report to address this fact. The results have been rationalized in terms of micellar kinetic studies in relation to the oxime structure. The reactivity of oximate ions in cationic micelles, as functionalized aggregates, as reactive polymers and metallomicelles has been well reviewed. Amidoximes emerging as versatile tool in detoxification chemistry has been discussed marginally in the present report. This article motivates similar kinds of studies from different viewpoints. Such studies can be extended to other micellar systems with versatile hydrophobic and hydrophilic properties.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of molecular liquids

ISSN

0167-7322

e-ISSN

—

Svazek periodika

208

Číslo periodika v rámci svazku

srpen

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

16

Strana od-do

237-252

Kód UT WoS článku

000357230700035

EID výsledku v databázi Scopus

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