Organotin(IV) derivatives containing heteroditopic pyridyl-quinolin-8-olate ligands: Synthesis and structures

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F21%3A50018227" target="_blank" >RIV/62690094:18470/21:50018227 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0022328X21002199" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0022328X21002199</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2021.121898" target="_blank" >10.1016/j.jorganchem.2021.121898</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Organotin(IV) derivatives containing heteroditopic pyridyl-quinolin-8-olate ligands: Synthesis and structures

Popis výsledku v původním jazyce

Six novel neutral organotin(IV) complexes, viz. [n-Bu2Sn(L4-PyAQ)(2)] 1 , [Bz(2)Sn(L4-PyAQ)(2)] 2 , [Ph2Sn(L4-PyAQ)(2)] 3 , [Ph2Sn(L3-PyAQ)(2)] 4 , [Bz(3)Sn(L4-PyAQ)] 5 and [Ph3Sn(L4-PyAQ)] 6 have been synthesized via reactions of 3/4-pyridyl-quinolin-8-ol pro-ligands, with appropriate diorganotin oxide and triorganotin hydroxide precursors, respectively. The compounds 1 6 were characterized in solution by means of NMR spectroscopy while the solid-state structures of 1, 6 , and of the solvates 2.1.5C(6)H(6), 3.0.25C(6)H(6), 2.4.C6H6, and 5.0.5H(2)O were authenticated by single crystal X-ray diffraction analysis. In the solid-state, the tin centers in 1- 2.4.C6H6 are hexacoordinated and reveal a distorted cis-octahedral environment. In 5.0.5H(2)O and 6 , the tin centers are pentacoordinated and show a coordination environment between trigonal-bipyramidal and square pyramidal.

Název v anglickém jazyce

Organotin(IV) derivatives containing heteroditopic pyridyl-quinolin-8-olate ligands: Synthesis and structures

Popis výsledku anglicky

Six novel neutral organotin(IV) complexes, viz. [n-Bu2Sn(L4-PyAQ)(2)] 1 , [Bz(2)Sn(L4-PyAQ)(2)] 2 , [Ph2Sn(L4-PyAQ)(2)] 3 , [Ph2Sn(L3-PyAQ)(2)] 4 , [Bz(3)Sn(L4-PyAQ)] 5 and [Ph3Sn(L4-PyAQ)] 6 have been synthesized via reactions of 3/4-pyridyl-quinolin-8-ol pro-ligands, with appropriate diorganotin oxide and triorganotin hydroxide precursors, respectively. The compounds 1 6 were characterized in solution by means of NMR spectroscopy while the solid-state structures of 1, 6 , and of the solvates 2.1.5C(6)H(6), 3.0.25C(6)H(6), 2.4.C6H6, and 5.0.5H(2)O were authenticated by single crystal X-ray diffraction analysis. In the solid-state, the tin centers in 1- 2.4.C6H6 are hexacoordinated and reveal a distorted cis-octahedral environment. In 5.0.5H(2)O and 6 , the tin centers are pentacoordinated and show a coordination environment between trigonal-bipyramidal and square pyramidal.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of organometallic chemistry

ISSN

0022-328X

e-ISSN

—

Svazek periodika

946-947

Číslo periodika v rámci svazku

August

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

11

Strana od-do

"Article Number: 121898"

Kód UT WoS článku

000663511600003

EID výsledku v databázi Scopus

2-s2.0-85107415076