SbI3 center dot 3S(8): A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F23%3A50020226" target="_blank" >RIV/62690094:18470/23:50020226 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/1996-1944/16/3/1105" target="_blank" >https://www.mdpi.com/1996-1944/16/3/1105</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma16031105" target="_blank" >10.3390/ma16031105</a>

Jazyk výsledku

angličtina

Název v původním jazyce

SbI3 center dot 3S(8): A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

Popis výsledku v původním jazyce

In the past twenty years, the basic investigation of innovative Non-Linear Optical (NLO) crystals has received significant attention, which has built the crucial heritage for the use of NLO materials. Fundamental research is essential given the scarcity of materials for NLO compounds, especially in the deep ultraviolet (DUV) and middle- and far-infrared (MFIR) regions. In the present work, we synthesized high-quality MFIR SbI3 center dot 3S(8) NLO crystals having a length in the range of 1-5 mm through rapid facile liquid phase ultrasonic reaction followed by the assistance of instantaneous natural evaporation phenomenon of the solvent at room temperature. X-ray diffraction (XRD) results ratify the hexagonal R3m structure of SbI3 center dot 3S(8) crystal, and energy-dispersive X-ray spectroscopy (EDX) demonstrates that the elemental composition of SbI3 center dot 3S(8) crystal is similar to that of its theoretical composition. The direct and indirect forbidden energy gaps of SbI3 center dot 3S(8) were measured from the optical transmittance spectra and they were shown to be 2.893 eV and 1.986 eV, respectively. The green sparkling signal has been observed from the crystal during the second harmonic generation (SHG) experiment. Therefore, as inorganic adducts are often explored as NLO crystals, this work on the MFIR SbI3 center dot 3S(8) NLO crystal can bring about additional investigations on this hot topic in the near future.

Název v anglickém jazyce

SbI3 center dot 3S(8): A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

Popis výsledku anglicky

In the past twenty years, the basic investigation of innovative Non-Linear Optical (NLO) crystals has received significant attention, which has built the crucial heritage for the use of NLO materials. Fundamental research is essential given the scarcity of materials for NLO compounds, especially in the deep ultraviolet (DUV) and middle- and far-infrared (MFIR) regions. In the present work, we synthesized high-quality MFIR SbI3 center dot 3S(8) NLO crystals having a length in the range of 1-5 mm through rapid facile liquid phase ultrasonic reaction followed by the assistance of instantaneous natural evaporation phenomenon of the solvent at room temperature. X-ray diffraction (XRD) results ratify the hexagonal R3m structure of SbI3 center dot 3S(8) crystal, and energy-dispersive X-ray spectroscopy (EDX) demonstrates that the elemental composition of SbI3 center dot 3S(8) crystal is similar to that of its theoretical composition. The direct and indirect forbidden energy gaps of SbI3 center dot 3S(8) were measured from the optical transmittance spectra and they were shown to be 2.893 eV and 1.986 eV, respectively. The green sparkling signal has been observed from the crystal during the second harmonic generation (SHG) experiment. Therefore, as inorganic adducts are often explored as NLO crystals, this work on the MFIR SbI3 center dot 3S(8) NLO crystal can bring about additional investigations on this hot topic in the near future.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

MATERIALS

ISSN

1996-1944

e-ISSN

1996-1944

Svazek periodika

16

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

12

Strana od-do

"Article Number: 1105"

Kód UT WoS článku

000932787300001

EID výsledku v databázi Scopus

2-s2.0-85147852904