Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn - N, N → Sn, and N - H⋅⋅⋅X (X = N, O) Interactions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F24%3A50021650" target="_blank" >RIV/62690094:18470/24:50021650 - isvavai.cz</a>
Výsledek na webu
<a href="https://link.springer.com/article/10.1007/s10904-024-03129-w" target="_blank" >https://link.springer.com/article/10.1007/s10904-024-03129-w</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10904-024-03129-w" target="_blank" >10.1007/s10904-024-03129-w</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn - N, N → Sn, and N - H⋅⋅⋅X (X = N, O) Interactions
Popis výsledku v původním jazyce
The multitopic heterofunctional pro-ligand 4-[(E)-(1H-imidazol-2-yl)diazenyl]benzoic acid (H ' HL) was synthesized by diazotization of 4-aminobenzoic acid followed by coupling with imidazole. Reactions of H ' HL (where H = imidazole proton and H ' = carboxylic acid proton) with the triorganotin precursors (Pr3SnCl)-Pr-n, ((Bu3Sn)-Bu-n)(2)O and Ph3SnOH provided three hypercoordinated triorganotin complexes, viz., [(Pr3Sn)-Pr-n(mu(4)-L)(SnPr3)-Pr-n](n)& sdot;1/8nEtOH (1), [(Bu3Sn)-Bu-n(mu-HL)](n) (2) and [Ph3Sn(HL)]& sdot;0.5C(6)H(6) (3), with complex 2D and 3D frameworks based on Sn - O, O -> Sn, Sn - N and N -> Sn metal-ligand bonds as well as N - H & sdot;& sdot;& sdot;N, N - H & sdot;& sdot;& sdot;O and pi-interactions. The compositions and structures of 1-3 in solution and in the solid-state were unambiguously established by NMR (H-1, C-13, Sn-119) and IR spectroscopy, UV-Vis spectral analysis, high-resolution mass spectrometry (HRMS) and single-crystal X-ray diffraction (scXRD) studies accompanied by Hirshfeld surface maps and 2D fingerprint plots.
Název v anglickém jazyce
Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn - N, N → Sn, and N - H⋅⋅⋅X (X = N, O) Interactions
Popis výsledku anglicky
The multitopic heterofunctional pro-ligand 4-[(E)-(1H-imidazol-2-yl)diazenyl]benzoic acid (H ' HL) was synthesized by diazotization of 4-aminobenzoic acid followed by coupling with imidazole. Reactions of H ' HL (where H = imidazole proton and H ' = carboxylic acid proton) with the triorganotin precursors (Pr3SnCl)-Pr-n, ((Bu3Sn)-Bu-n)(2)O and Ph3SnOH provided three hypercoordinated triorganotin complexes, viz., [(Pr3Sn)-Pr-n(mu(4)-L)(SnPr3)-Pr-n](n)& sdot;1/8nEtOH (1), [(Bu3Sn)-Bu-n(mu-HL)](n) (2) and [Ph3Sn(HL)]& sdot;0.5C(6)H(6) (3), with complex 2D and 3D frameworks based on Sn - O, O -> Sn, Sn - N and N -> Sn metal-ligand bonds as well as N - H & sdot;& sdot;& sdot;N, N - H & sdot;& sdot;& sdot;O and pi-interactions. The compositions and structures of 1-3 in solution and in the solid-state were unambiguously established by NMR (H-1, C-13, Sn-119) and IR spectroscopy, UV-Vis spectral analysis, high-resolution mass spectrometry (HRMS) and single-crystal X-ray diffraction (scXRD) studies accompanied by Hirshfeld surface maps and 2D fingerprint plots.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10401 - Organic chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2024
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Inorganic and Organometallic Polymers and Materials
ISSN
1574-1443
e-ISSN
1574-1451
Svazek periodika
34
Číslo periodika v rámci svazku
7
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
19
Strana od-do
3281-3299
Kód UT WoS článku
001234282300001
EID výsledku v databázi Scopus
2-s2.0-85194566962