Izotermní rovnováha kapalina-pára s chemickou reakcí ve čtyřsložkové soustavě voda + methanol + kyselina octová + methylacetát, a v pěti binárních subsystémech.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F06%3A00081859" target="_blank" >RIV/67985858:_____/06:00081859 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems.

Popis výsledku v původním jazyce

Vapour-liquid equilibrium accompanied with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system was measured in a circulation still; 20 experimental points at 323.15 K were determined. For the complete and consistentdescription, the isothermal VLE data in the four non-reacting binary subsystems were measured, too. The data were correlated by means of the maximum likelihood procedure by using the NRTL model; binary model parameters for the binary subsystems were obtained from experimental vapour?liquid equilibrium data by using either the Hayden?O'Connell or Marek?Standart correction as appropriate, to account for the non-ideality of vapour phase. NRTL parameters for the reacting binary subsystems were estimated from the global optimization based on the quaternary experimental data. By using transformed composition variables, two?dimensional phase diagrams for the quaternary system have been constructed.

Název v anglickém jazyce

Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems.

Popis výsledku anglicky

Vapour-liquid equilibrium accompanied with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system was measured in a circulation still; 20 experimental points at 323.15 K were determined. For the complete and consistentdescription, the isothermal VLE data in the four non-reacting binary subsystems were measured, too. The data were correlated by means of the maximum likelihood procedure by using the NRTL model; binary model parameters for the binary subsystems were obtained from experimental vapour?liquid equilibrium data by using either the Hayden?O'Connell or Marek?Standart correction as appropriate, to account for the non-ideality of vapour phase. NRTL parameters for the reacting binary subsystems were estimated from the global optimization based on the quaternary experimental data. By using transformed composition variables, two?dimensional phase diagrams for the quaternary system have been constructed.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA203%2F03%2F1588" target="_blank" >GA203/03/1588: Fázové rovnováhy v reagujících soustavách</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2006

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Fluid Phase Equilibria

ISSN

0378-3812

e-ISSN

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Svazek periodika

247

Číslo periodika v rámci svazku

1-2

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

6

Strana od-do

96-101

Kód UT WoS článku

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EID výsledku v databázi Scopus

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