Vapour?Liquid and Chemical Equilibria in the Ethyl Ethanoate + Ethanol + Propyl Ethanoate + Propanol System Accompanied with Transesterification Reaction

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F12%3A00377896" target="_blank" >RIV/67985858:_____/12:00377896 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.fluid.2012.05.016" target="_blank" >http://dx.doi.org/10.1016/j.fluid.2012.05.016</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.fluid.2012.05.016" target="_blank" >10.1016/j.fluid.2012.05.016</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Vapour?Liquid and Chemical Equilibria in the Ethyl Ethanoate + Ethanol + Propyl Ethanoate + Propanol System Accompanied with Transesterification Reaction

Popis výsledku v původním jazyce

Phase and chemical equilibria in the quaternary ethyl ethanoate + ethanol + propyl ethanoate + propanol system and in all six binary subsystems has been investigated at two isotherms, namely at 323.15 and 348.15 K. In total, 116 quaternary experimental points were determined. The binary data were correlated by means of the NRTL model using a robust approach and the maximum likelihood procedure. The binary parameters obtained were used for prediction of vapour?liquid equilibria in the quaternary system and results show a good agreement of calculated and experimental data. The three?dimensional phase diagrams for the quaternary system have been constructed with use of transformed compositions.

Název v anglickém jazyce

Vapour?Liquid and Chemical Equilibria in the Ethyl Ethanoate + Ethanol + Propyl Ethanoate + Propanol System Accompanied with Transesterification Reaction

Popis výsledku anglicky

Phase and chemical equilibria in the quaternary ethyl ethanoate + ethanol + propyl ethanoate + propanol system and in all six binary subsystems has been investigated at two isotherms, namely at 323.15 and 348.15 K. In total, 116 quaternary experimental points were determined. The binary data were correlated by means of the NRTL model using a robust approach and the maximum likelihood procedure. The binary parameters obtained were used for prediction of vapour?liquid equilibria in the quaternary system and results show a good agreement of calculated and experimental data. The three?dimensional phase diagrams for the quaternary system have been constructed with use of transformed compositions.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA104%2F07%2F0444" target="_blank" >GA104/07/0444: Termodynamické vlastnosti soustav kapalina-plyn</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Fluid Phase Equilibria

ISSN

0378-3812

e-ISSN

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Svazek periodika

328

Číslo periodika v rámci svazku

AUG 25

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

6

Strana od-do

61-68

Kód UT WoS článku

000307132900009

EID výsledku v databázi Scopus

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