Homogeneous Catalytic Transfer Hydrogenation in Microfluidic Flow System

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F14%3A00431190" target="_blank" >RIV/67985858:_____/14:00431190 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Homogeneous Catalytic Transfer Hydrogenation in Microfluidic Flow System

Popis výsledku v původním jazyce

The microreactor technology is an intensively developing field containing various types of microreactor systems possessing many advantageous features. The most important feature is their high active surface-to-volume ratio ensuring the excellent controlof the local reaction conditions as well as the high heat, mass and momentum transfer. We present a novel MSR application - the homogeneous catalytic transfer hydrogenation. Catalytic transfer hydrogenations use organic compounds both as solvents and hydrogen sources. These hydrogenations are commonly catalyzed by metallic complexes such as Ru-BINAP referred to be the most active catalyst for obtaining a high enantiomeric excess, yield and activity of enantioselective reactions. We report a study wherea glass microfluidic reactor was tested for the model reaction of the hydrogenation of methyl acetoacetate. Obtained experimental results were compared with those of the conventional reactor tests published in literature.

Název v anglickém jazyce

Homogeneous Catalytic Transfer Hydrogenation in Microfluidic Flow System

Popis výsledku anglicky

The microreactor technology is an intensively developing field containing various types of microreactor systems possessing many advantageous features. The most important feature is their high active surface-to-volume ratio ensuring the excellent controlof the local reaction conditions as well as the high heat, mass and momentum transfer. We present a novel MSR application - the homogeneous catalytic transfer hydrogenation. Catalytic transfer hydrogenations use organic compounds both as solvents and hydrogen sources. These hydrogenations are commonly catalyzed by metallic complexes such as Ru-BINAP referred to be the most active catalyst for obtaining a high enantiomeric excess, yield and activity of enantioselective reactions. We report a study wherea glass microfluidic reactor was tested for the model reaction of the hydrogenation of methyl acetoacetate. Obtained experimental results were compared with those of the conventional reactor tests published in literature.

Druh

D - Stať ve sborníku

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Book of Abstracts

ISBN

978-963-05-9518-6

ISSN

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e-ISSN

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Počet stran výsledku

2

Strana od-do

207-208

Název nakladatele

Budapest University of Technology and Economics

Místo vydání

Budapest

Místo konání akce

Budapest

Datum konání akce

23. 6. 2014

Typ akce podle státní příslušnosti

EUR - Evropská akce

Kód UT WoS článku

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