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Recent Progress in Molecular Simulation of Aqueous Electrolytes: Force Fields, Chemical Potentials and Solubility.

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00466027" target="_blank" >RIV/67985858:_____/16:00466027 - isvavai.cz</a>

  • Nalezeny alternativní kódy

    RIV/44555601:13440/16:43887784

  • Výsledek na webu

    <a href="http://dx.doi.org/10.1080/00268976.2016.1165296" target="_blank" >http://dx.doi.org/10.1080/00268976.2016.1165296</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1080/00268976.2016.1165296" target="_blank" >10.1080/00268976.2016.1165296</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Recent Progress in Molecular Simulation of Aqueous Electrolytes: Force Fields, Chemical Potentials and Solubility.

  • Popis výsledku v původním jazyce

    Although aqueous electrolytes are among the most important solutions, the molecular simulation of their intertwined properties of chemical potentials, solubility and activity coefficients has remained a challenging problem, and has attracted considerable recent interest. In this perspectives review, we focus on the simplest case of aqueous sodium chloride at ambient conditions and discuss the two main factors that have impeded progress. The first is lack of consensus with respect to the appropriate methodology for force field (FF) development. We examine how most commonly used FFs have been developed, and emphasise the importance of distinguishing between 'Training Set Properties' used to fit the FF parameters, and 'Test Set Properties', which are pure predictions of additional properties. The second is disagreement among solubility results obtained, even using identical FFs and thermodynamic conditions. Solubility calculations have been approached using both thermodynamic-based methods and direct molecular dynamics-based methods implementing coexisting solution and solid phases. Although convergence has been very recently achieved among results based on the former approach, there is as yet no general agreement with simulation results based on the latter methodology. We also propose a new method to directly calculate the electrolyte standard chemical potential in the Henry law ideality model. We conclude by making recommendations for calculating solubility, chemical potentials and activity coefficients, and outline a potential path for future progress.

  • Název v anglickém jazyce

    Recent Progress in Molecular Simulation of Aqueous Electrolytes: Force Fields, Chemical Potentials and Solubility.

  • Popis výsledku anglicky

    Although aqueous electrolytes are among the most important solutions, the molecular simulation of their intertwined properties of chemical potentials, solubility and activity coefficients has remained a challenging problem, and has attracted considerable recent interest. In this perspectives review, we focus on the simplest case of aqueous sodium chloride at ambient conditions and discuss the two main factors that have impeded progress. The first is lack of consensus with respect to the appropriate methodology for force field (FF) development. We examine how most commonly used FFs have been developed, and emphasise the importance of distinguishing between 'Training Set Properties' used to fit the FF parameters, and 'Test Set Properties', which are pure predictions of additional properties. The second is disagreement among solubility results obtained, even using identical FFs and thermodynamic conditions. Solubility calculations have been approached using both thermodynamic-based methods and direct molecular dynamics-based methods implementing coexisting solution and solid phases. Although convergence has been very recently achieved among results based on the former approach, there is as yet no general agreement with simulation results based on the latter methodology. We also propose a new method to directly calculate the electrolyte standard chemical potential in the Henry law ideality model. We conclude by making recommendations for calculating solubility, chemical potentials and activity coefficients, and outline a potential path for future progress.

Klasifikace

  • Druh

    J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

  • CEP obor

    CF - Fyzikální chemie a teoretická chemie

  • OECD FORD obor

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/GA15-19542S" target="_blank" >GA15-19542S: Termodynamika roztoků polymerů: experimenty jdou naproti teorii (a obráceně)</a><br>

  • Návaznosti

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Ostatní

  • Rok uplatnění

    2016

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Molecular Physics

  • ISSN

    0026-8976

  • e-ISSN

  • Svazek periodika

    114

  • Číslo periodika v rámci svazku

    11

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    26

  • Strana od-do

    1665-1690

  • Kód UT WoS článku

    000376867200001

  • EID výsledku v databázi Scopus

    2-s2.0-84962090129