Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F17%3A00483420" target="_blank" >RIV/67985858:_____/17:00483420 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/17:00483420 RIV/00216224:14310/17:00099179 RIV/61989592:15110/17:73583211 RIV/00216275:25310/17:39912069

Výsledek na webu

<a href="http://dx.doi.org/10.1002/celc.201700441" target="_blank" >http://dx.doi.org/10.1002/celc.201700441</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/celc.201700441" target="_blank" >10.1002/celc.201700441</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers.

Popis výsledku v původním jazyce

New materials bearing thiophene and helicene moieties were prepared by using a potential-driven on/off switch strategy on the surface of glassy carbon and indium tin oxide substrates. Specifically, a 3-([7]helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by using cyclic voltammetry with anodic potential limits of +1.5 or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations, UV/Vis, fluorescence and vibrational spectroscopies, and 1H NMR spectroscopy as well as ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics, optoelectronics, and sensing technologies.

Název v anglickém jazyce

Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers.

Popis výsledku anglicky

New materials bearing thiophene and helicene moieties were prepared by using a potential-driven on/off switch strategy on the surface of glassy carbon and indium tin oxide substrates. Specifically, a 3-([7]helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by using cyclic voltammetry with anodic potential limits of +1.5 or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations, UV/Vis, fluorescence and vibrational spectroscopies, and 1H NMR spectroscopy as well as ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics, optoelectronics, and sensing technologies.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ChemElectroChem

ISSN

2196-0216

e-ISSN

—

Svazek periodika

4

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

6

Strana od-do

3047-3052

Kód UT WoS článku

000419269000004

EID výsledku v databázi Scopus

2-s2.0-85027503424