Liquid-liquid equilibria in systems of ionic liquids: A guide to experiments and data analysis

Kód výsledku v IS VaVaI

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Výsledek na webu

<a href="https://books.google.cz/books?id=R3acDwAAQBAJ&pg=PA17&lpg=PA17&dq=10.1515/9783110583632-002&source=bl&ots=6qk2b8cloa&sig=ACfU3U151oxWRVzD-pQUqHdCX7WA1NZVUg&hl=cs&sa=X&ved=2ahUKEwj4gaqxiqvnAhVKZVAKHfSxAQ0Q6AEwBHoECAMQAQ#v=onepage&q=10.1515%2F9783110583632-002&f=false" target="_blank" >https://books.google.cz/books?id=R3acDwAAQBAJ&pg=PA17&lpg=PA17&dq=10.1515/9783110583632-002&source=bl&ots=6qk2b8cloa&sig=ACfU3U151oxWRVzD-pQUqHdCX7WA1NZVUg&hl=cs&sa=X&ved=2ahUKEwj4gaqxiqvnAhVKZVAKHfSxAQ0Q6AEwBHoECAMQAQ#v=onepage&q=10.1515%2F9783110583632-002&f=false</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1515/9783110583632-002" target="_blank" >10.1515/9783110583632-002</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Liquid-liquid equilibria in systems of ionic liquids: A guide to experiments and data analysis

Popis výsledku v původním jazyce

Experimental methods used to determine liquid-liquid equilibria (LLE) in systems con-taining ionic liquids (Its) are summarized. While these methods are essentially the same as in studies of LLE in systems of molecular liquids, systems containing ILs show some specificities that must be taken into account. The methods addressed are therefore compared and assessed as to their suitability, advantages and drawbacks.nIn the second part of the chapter, data analysis is addressed to demonstrate the wealth of information that can be obtained by means of using appropriate methods. An example of multivariate calibration using the partial least-squares method is given to show the means of separating overlapping UV-Vis spectra. Most importantly, though, a brief introduction to mathematical gnostics is given. This nonsta- tistical approach to data uncertainty is a powerful tool in critical assessment of a number of types of thermodynamic data, including LLE, and in a robust linear as well as nonline-ar regression even of small samples of scattered data.n

Název v anglickém jazyce

Liquid-liquid equilibria in systems of ionic liquids: A guide to experiments and data analysis

Popis výsledku anglicky

Experimental methods used to determine liquid-liquid equilibria (LLE) in systems con-taining ionic liquids (Its) are summarized. While these methods are essentially the same as in studies of LLE in systems of molecular liquids, systems containing ILs show some specificities that must be taken into account. The methods addressed are therefore compared and assessed as to their suitability, advantages and drawbacks.nIn the second part of the chapter, data analysis is addressed to demonstrate the wealth of information that can be obtained by means of using appropriate methods. An example of multivariate calibration using the partial least-squares method is given to show the means of separating overlapping UV-Vis spectra. Most importantly, though, a brief introduction to mathematical gnostics is given. This nonsta- tistical approach to data uncertainty is a powerful tool in critical assessment of a number of types of thermodynamic data, including LLE, and in a robust linear as well as nonline-ar regression even of small samples of scattered data.n

Druh

C - Kapitola v odborné knize

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Ionic Liquids. Synthesis, Properties, Technologies and Applications

ISBN

978-3-11-058201-7

Počet stran výsledku

11

Strana od-do

17-27

Počet stran knihy

163

Název nakladatele

Walter de Gruyter GmbH

Místo vydání

Brlin

Kód UT WoS kapitoly

—