Calcination Temperature on N2O Conversion in the Presence of H2O and NOx

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F20%3A00540440" target="_blank" >RIV/67985858:_____/20:00540440 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.3390/catal10101134" target="_blank" >http://dx.doi.org/10.3390/catal10101134</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal10101134" target="_blank" >10.3390/catal10101134</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Calcination Temperature on N2O Conversion in the Presence of H2O and NOx

Popis výsledku v původním jazyce

The effect of calcination temperature (500-700 degrees C) on physico-chemical properties and catalytic activity of 2 wt. % K/Co-Mn-Al mixed oxide for N2O decomposition was investigated. Catalysts were characterized by inductively coupled plasma spectroscopy (ICP), X-ray powder diffraction (XRD), temperature-programmed reduction by hydrogen (TPR-H-2), temperature-programmed desorption of CO2 (TPD-CO2), temperature-programmed desorption of NO (TPD-NO), X-ray photoelectron spectrometry (XPS) and N-2 physisorption. It was found that the increase in calcination temperature caused gradual crystallization of Co-Mn-Al mixed oxide, which manifested itself in the decrease in Co2+/Co3+ and Mn3+/Mn4+ surface molar ratio, the increase in mean crystallite size leading to lowering of specific surface area and poorer reducibility. Higher surface K content normalized per unit surface led to the increase in surface basicity and adsorbed NO per unit surface. The effect of calcination temperature on catalytic activity was significant mainly in the presence of NOx, as the optimal calcination temperature of 500 degrees C is necessary to ensure sufficient low surface basicity, leading to the highest catalytic activity. Observed NO inhibition was caused by the formation of surface mononitrosyl species bonded to tetrahedral metal sites or nitrite species, which are stable at reaction temperatures up to 450 degrees C and block active sites for N2O decomposition.

Název v anglickém jazyce

Calcination Temperature on N2O Conversion in the Presence of H2O and NOx

Popis výsledku anglicky

The effect of calcination temperature (500-700 degrees C) on physico-chemical properties and catalytic activity of 2 wt. % K/Co-Mn-Al mixed oxide for N2O decomposition was investigated. Catalysts were characterized by inductively coupled plasma spectroscopy (ICP), X-ray powder diffraction (XRD), temperature-programmed reduction by hydrogen (TPR-H-2), temperature-programmed desorption of CO2 (TPD-CO2), temperature-programmed desorption of NO (TPD-NO), X-ray photoelectron spectrometry (XPS) and N-2 physisorption. It was found that the increase in calcination temperature caused gradual crystallization of Co-Mn-Al mixed oxide, which manifested itself in the decrease in Co2+/Co3+ and Mn3+/Mn4+ surface molar ratio, the increase in mean crystallite size leading to lowering of specific surface area and poorer reducibility. Higher surface K content normalized per unit surface led to the increase in surface basicity and adsorbed NO per unit surface. The effect of calcination temperature on catalytic activity was significant mainly in the presence of NOx, as the optimal calcination temperature of 500 degrees C is necessary to ensure sufficient low surface basicity, leading to the highest catalytic activity. Observed NO inhibition was caused by the formation of surface mononitrosyl species bonded to tetrahedral metal sites or nitrite species, which are stable at reaction temperatures up to 450 degrees C and block active sites for N2O decomposition.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

—

Svazek periodika

10

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

17

Strana od-do

1134

Kód UT WoS článku

000583992900001

EID výsledku v databázi Scopus

2-s2.0-85091899998