CO2 separation of fluorinated 6FDA-based polyimides, performance-improved ZIF-incorporated mixed matrix membranes and gas permeability model evaluations.
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F22%3A00564059" target="_blank" >RIV/67985858:_____/22:00564059 - isvavai.cz</a>
Výsledek na webu
<a href="https://hdl.handle.net/11104/0335804" target="_blank" >https://hdl.handle.net/11104/0335804</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jece.2022.108611" target="_blank" >10.1016/j.jece.2022.108611</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
CO2 separation of fluorinated 6FDA-based polyimides, performance-improved ZIF-incorporated mixed matrix membranes and gas permeability model evaluations.
Popis výsledku v původním jazyce
In this study, we compare a newly introduced high free volume fluorinated 6FDA-polyimide, namely 6FDA-bisP, with excellent gas separation properties (CO2 permeability, PCO2 of 35.3 Barrer, CO2/CH4 selectivity, alpha CO2/CH4 of 25.5) to the well-investigated, lower free volume 6FDA-ODA (PCO2 = 25.9 Barrer, alpha CO2/CH4 = 20.6). Their gas separation performances were improved in the form of mixed matrix membranes (MMMs) with size sieving zeolitic imidazolate framework (ZIF-8, particle range of <160 nm) addition between 5 and 20 wt% loadings. XRD, BET, FTIR, TGA, DSC, SEM, and TEM were used to characterize the nanoparticles and MMMs. Solid density was obtained from He pycnometry analysis (pressurized cycle test between 2 and 20 bar at 20 <degrees>C) to calculate the free fractional volume (FFV). Using an equimolar CO2 and CH4 mixture, gas separation performance was evaluated at a constant 5 bar, at 25 degrees C. The optimum loading was achieved at 15 wt% for 6FDA-bisP with MMM performance of PCO2 = 81.2 Barrer and alpha CO2/CH4 = 35.0, whereas 10 wt% for 6FDA-ODA (PCO2 = 42.2 Barrer, alpha CO2/CH4 = 44.8). The MMMs showed superior performances than the currently relevant polymers in industrial separation processes. Four different gas permeability models: Maxwell, Maxwell-Wagner-Sillar, Higuchi and Lewis Nielsen, were utilized to analyze the obtained data.
Název v anglickém jazyce
CO2 separation of fluorinated 6FDA-based polyimides, performance-improved ZIF-incorporated mixed matrix membranes and gas permeability model evaluations.
Popis výsledku anglicky
In this study, we compare a newly introduced high free volume fluorinated 6FDA-polyimide, namely 6FDA-bisP, with excellent gas separation properties (CO2 permeability, PCO2 of 35.3 Barrer, CO2/CH4 selectivity, alpha CO2/CH4 of 25.5) to the well-investigated, lower free volume 6FDA-ODA (PCO2 = 25.9 Barrer, alpha CO2/CH4 = 20.6). Their gas separation performances were improved in the form of mixed matrix membranes (MMMs) with size sieving zeolitic imidazolate framework (ZIF-8, particle range of <160 nm) addition between 5 and 20 wt% loadings. XRD, BET, FTIR, TGA, DSC, SEM, and TEM were used to characterize the nanoparticles and MMMs. Solid density was obtained from He pycnometry analysis (pressurized cycle test between 2 and 20 bar at 20 <degrees>C) to calculate the free fractional volume (FFV). Using an equimolar CO2 and CH4 mixture, gas separation performance was evaluated at a constant 5 bar, at 25 degrees C. The optimum loading was achieved at 15 wt% for 6FDA-bisP with MMM performance of PCO2 = 81.2 Barrer and alpha CO2/CH4 = 35.0, whereas 10 wt% for 6FDA-ODA (PCO2 = 42.2 Barrer, alpha CO2/CH4 = 44.8). The MMMs showed superior performances than the currently relevant polymers in industrial separation processes. Four different gas permeability models: Maxwell, Maxwell-Wagner-Sillar, Higuchi and Lewis Nielsen, were utilized to analyze the obtained data.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20402 - Chemical process engineering
Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Environmental Chemical Engineering
ISSN
2213-3437
e-ISSN
2213-3437
Svazek periodika
10
Číslo periodika v rámci svazku
6
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
13
Strana od-do
108611
Kód UT WoS článku
000875614200004
EID výsledku v databázi Scopus
2-s2.0-85144301197