Electrochemistry of different boranes, carbaboranes and their exo-skeletal hydroxy derivatives at the graphite carbon electrode in aqueous phosphate buffers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F16%3A00460918" target="_blank" >RIV/68081707:_____/16:00460918 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61388980:_____/16:00460918 RIV/00216224:14740/16:00088691

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.electacta.2016.04.106" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2016.04.106</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2016.04.106" target="_blank" >10.1016/j.electacta.2016.04.106</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemistry of different boranes, carbaboranes and their exo-skeletal hydroxy derivatives at the graphite carbon electrode in aqueous phosphate buffers

Popis výsledku v původním jazyce

Electrochemical behavior of four cluster boranes and nine derivatives of ten-and eleven-vertex cluster boranes has been studied in phosphate buffers. These compounds show promising applications in biological sciences and in biomedicine and, therefore, analytical techniques developed for their determination and analysis of their bioconjugates should be compatible with aqueous media. Results presented herein show that both endo-and exo-skeletal substitutions of cluster boranes significantly influence their electrochemical responses, such as the shape of voltammetric curves, the position of the current maximum in a potential scale, and the peak current density. Selected substitutions can be utilized to tune electrochemical properties of the boron cluster compounds in order to optimize their responses for their electroanalytical determination and their usage as labels for biopolymers.

Název v anglickém jazyce

Electrochemistry of different boranes, carbaboranes and their exo-skeletal hydroxy derivatives at the graphite carbon electrode in aqueous phosphate buffers

Popis výsledku anglicky

Electrochemical behavior of four cluster boranes and nine derivatives of ten-and eleven-vertex cluster boranes has been studied in phosphate buffers. These compounds show promising applications in biological sciences and in biomedicine and, therefore, analytical techniques developed for their determination and analysis of their bioconjugates should be compatible with aqueous media. Results presented herein show that both endo-and exo-skeletal substitutions of cluster boranes significantly influence their electrochemical responses, such as the shape of voltammetric curves, the position of the current maximum in a potential scale, and the peak current density. Selected substitutions can be utilized to tune electrochemical properties of the boron cluster compounds in order to optimize their responses for their electroanalytical determination and their usage as labels for biopolymers.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BO - Biofyzika

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Electrochimica acta

ISSN

0013-4686

e-ISSN

—

Svazek periodika

205

Číslo periodika v rámci svazku

JUL 2016

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

8-14

Kód UT WoS článku

000376138600002

EID výsledku v databázi Scopus

2-s2.0-84965020559