Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F18%3A00535968" target="_blank" >RIV/68081707:_____/18:00535968 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/18:10392223

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/B9780128138557000039" target="_blank" >https://www.sciencedirect.com/science/article/pii/B9780128138557000039</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/B978-0-12-813855-7.00003-9" target="_blank" >10.1016/B978-0-12-813855-7.00003-9</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups

Popis výsledku v původním jazyce

In this chapter we focus on the properties of graphitic carbon and boron-doped diamond (BDD) electrodes from the point of view of surface micro- and nanostructures, chemistry of surface termination, effects of these characteristics on electron transfer and adsorption characteristics of the electrodes. Their properties are discussed in relation to electrochemical responses measured for typical groups of analytes, such as nucleic acid and protein constituents or other electroactive compounds. In general, basal planes of graphitic materials are sites of preferential adsorption of organic compounds while the edge planes and defects are sites of fast electron transfer for a number of analytes. At the BDD, fast electron transfer kinetics is observed particularly at hydrogenated and polished surfaces. Surface termination with oxygenous groups causes the electron transfer rate to decrease and renders the carbon surface hydrophilic properties, manifested in decreased adsorption of hydrophobic molecules and involvement of coulombic forces and hydrogen bonds in interactions of relevant analytes with the electrode surfaces. Examples of applications in the area of electroanalysis of biomolecules and their components are briefly discussed.nn

Název v anglickém jazyce

Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups

Popis výsledku anglicky

In this chapter we focus on the properties of graphitic carbon and boron-doped diamond (BDD) electrodes from the point of view of surface micro- and nanostructures, chemistry of surface termination, effects of these characteristics on electron transfer and adsorption characteristics of the electrodes. Their properties are discussed in relation to electrochemical responses measured for typical groups of analytes, such as nucleic acid and protein constituents or other electroactive compounds. In general, basal planes of graphitic materials are sites of preferential adsorption of organic compounds while the edge planes and defects are sites of fast electron transfer for a number of analytes. At the BDD, fast electron transfer kinetics is observed particularly at hydrogenated and polished surfaces. Surface termination with oxygenous groups causes the electron transfer rate to decrease and renders the carbon surface hydrophilic properties, manifested in decreased adsorption of hydrophobic molecules and involvement of coulombic forces and hydrogen bonds in interactions of relevant analytes with the electrode surfaces. Examples of applications in the area of electroanalysis of biomolecules and their components are briefly discussed.nn

Druh

C - Kapitola v odborné knize

CEP obor

—

OECD FORD obor

10608 - Biochemistry and molecular biology

Projekt

<a href="/cs/project/GBP206%2F12%2FG151" target="_blank" >GBP206/12/G151: Centrum nových přístupů k bioanalýze a molekulární diagnostice</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

NANOTECHNOLOGY AND BIOSENSORS

ISBN

978-0-12-813855-7

Počet stran výsledku

61

Strana od-do

"Roč. 2018"

Počet stran knihy

470

Název nakladatele

ELSEVIER SCIENCE BV

Místo vydání

AMSTERDAM, NETHERLANDS

Kód UT WoS kapitoly

000532363700004