Adsorption and 2D condensation of 5-nitrocytosine at the hanging mercury drop electrode

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F19%3A00518358" target="_blank" >RIV/68081707:_____/19:00518358 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1572665719305065?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1572665719305065?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jelechem.2019.113238" target="_blank" >10.1016/j.jelechem.2019.113238</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Adsorption and 2D condensation of 5-nitrocytosine at the hanging mercury drop electrode

Popis výsledku v původním jazyce

For first time, we have observed the two-dimensional (2D) condensation and adsorption of 5-nitrocytosine at the hanging mercury drop electrode in different electrolytes. The 2D condensation is a special form of the self-assembled monolayers of mainly organic compounds. The 5-nitrocytosine is adsorbed in broad range of pHs (2.5 to 9.5), whereas the 2D condensation could be identified only in acidic and neutral pH (up to pH = 7.1). Three different types of condensed layers were observed, dependent on the pH, temperature and concentration of 5-nitrocytosine. The 2D condensation of 5-nitrocytosine is stabilized by different driving forces, including the short range interactions and hydrogen bonding. The effect of different electrolytes containing Cl-, Br- and I- ions onto the 2D condensation was also investigated.

Název v anglickém jazyce

Adsorption and 2D condensation of 5-nitrocytosine at the hanging mercury drop electrode

Popis výsledku anglicky

For first time, we have observed the two-dimensional (2D) condensation and adsorption of 5-nitrocytosine at the hanging mercury drop electrode in different electrolytes. The 2D condensation is a special form of the self-assembled monolayers of mainly organic compounds. The 5-nitrocytosine is adsorbed in broad range of pHs (2.5 to 9.5), whereas the 2D condensation could be identified only in acidic and neutral pH (up to pH = 7.1). Three different types of condensed layers were observed, dependent on the pH, temperature and concentration of 5-nitrocytosine. The 2D condensation of 5-nitrocytosine is stabilized by different driving forces, including the short range interactions and hydrogen bonding. The effect of different electrolytes containing Cl-, Br- and I- ions onto the 2D condensation was also investigated.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

—

Svazek periodika

847

Číslo periodika v rámci svazku

AUG 15 2019

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

5

Strana od-do

113238

Kód UT WoS článku

000482532200045

EID výsledku v databázi Scopus

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