Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081715%3A_____%2F11%3A00362869" target="_blank" >RIV/68081715:_____/11:00362869 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1351/PAC-REP-09-10-03" target="_blank" >http://dx.doi.org/10.1351/PAC-REP-09-10-03</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1351/PAC-REP-09-10-03" target="_blank" >10.1351/PAC-REP-09-10-03</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)

Popis výsledku v původním jazyce

This report is focused on the rationalization and clarification of fundamental aspects related to CHG: mechanism of hydrolysis of borane complexes; mechanism of hydrogen transfer from the borane complex to the analytical substrate; mechanisms through which the different chemical reaction conditions control the CHG process; and mechanism of action of chemical additives and foreign species. Enhanced comprehension of these different mechanisms and their mutual influence can be achieved in light of the present state of knowledge. This provides the tools to explain the reactivity of a CHG system and contributes to the clarification of several controversial aspects and the elimination of erroneous concepts in CHG.

Název v anglickém jazyce

Mechanisms of chemical generation of volatile hydrides for trace element determination (IUPAC Technical Report)

Popis výsledku anglicky

This report is focused on the rationalization and clarification of fundamental aspects related to CHG: mechanism of hydrolysis of borane complexes; mechanism of hydrogen transfer from the borane complex to the analytical substrate; mechanisms through which the different chemical reaction conditions control the CHG process; and mechanism of action of chemical additives and foreign species. Enhanced comprehension of these different mechanisms and their mutual influence can be achieved in light of the present state of knowledge. This provides the tools to explain the reactivity of a CHG system and contributes to the clarification of several controversial aspects and the elimination of erroneous concepts in CHG.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CB - Analytická chemie, separace

OECD FORD obor

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Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Pure and Applied Chemistry

ISSN

0033-4545

e-ISSN

—

Svazek periodika

83

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

58

Strana od-do

1283-1340

Kód UT WoS článku

000290852100006

EID výsledku v databázi Scopus

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