Modeling of diffusional phase transformation in multi-component systems with stoichiometric phases

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F10%3A00352152" target="_blank" >RIV/68081723:_____/10:00352152 - isvavai.cz</a>

Výsledek na webu

—

DOI - Digital Object Identifier

—

Jazyk výsledku

angličtina

Název v původním jazyce

Modeling of diffusional phase transformation in multi-component systems with stoichiometric phases

Popis výsledku v původním jazyce

In many multi-component systems, phases can be considered stoichiometric. If two phases not stably coexisting are brought into contact, multiple new phases may nucleate at the interface and develop into a sequence of layers with different phase compositions, which grow between the original phases. Inert markers at the original contact may show ?splitting of the marker (Kirkendall) plane, called polyfurcation. Nearly exclusively binary systems have been studied theoretically or experimentally. A thermodynamic model for the kinetics of diffusional phase transformation in multi-component systems and motion of the polyfurcated Kirkendall plane is derived by the thermodynamic extremal principle. The degrees of freedom of the system are discussed rigorously.The model is demonstrated on simulations of kinetics in binary three-phase and ternary four-phase systems.

Název v anglickém jazyce

Modeling of diffusional phase transformation in multi-component systems with stoichiometric phases

Popis výsledku anglicky

In many multi-component systems, phases can be considered stoichiometric. If two phases not stably coexisting are brought into contact, multiple new phases may nucleate at the interface and develop into a sequence of layers with different phase compositions, which grow between the original phases. Inert markers at the original contact may show ?splitting of the marker (Kirkendall) plane, called polyfurcation. Nearly exclusively binary systems have been studied theoretically or experimentally. A thermodynamic model for the kinetics of diffusional phase transformation in multi-component systems and motion of the polyfurcated Kirkendall plane is derived by the thermodynamic extremal principle. The degrees of freedom of the system are discussed rigorously.The model is demonstrated on simulations of kinetics in binary three-phase and ternary four-phase systems.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BJ - Termodynamika

OECD FORD obor

—

Projekt

<a href="/cs/project/OC10029" target="_blank" >OC10029: Termodynamické modelování vývoje mikrostruktury v nanokompozitech.</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Materialia

ISSN

1359-6454

e-ISSN

—

Svazek periodika

58

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

—

Kód UT WoS článku

000276736200011

EID výsledku v databázi Scopus

—