Modelling for hydrogen diffusion in metals with traps revisited

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F12%3A00369684" target="_blank" >RIV/68081723:_____/12:00369684 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Modelling for hydrogen diffusion in metals with traps revisited

Popis výsledku v původním jazyce

A rigorous concept for diffusion of hydrogen is presented that allows for the role of trapping and/or hydrostatic stress. Nonlinear partial differential equations for the concentration of freely diffusing hydrogen in the lattice and for the total concentration of hydrogen both in the lattice and traps are derived. A generalized chemical diffusion coefficient can be deduced and is compared with reported relations from the literature. Simulation results are presented for different amounts of traps and their different energetic levels (depths), both for hydrogen concentration profiles and the total amount of hydrogen in the case of charging or discharging a cylindrical specimen. A significant charging/discharging asymmetry occurs for high hydrogen concentrations and high amounts of traps of sufficient depth. Comparisons of the chemical diffusion coefficient with experimental results from the literature are also presented.

Název v anglickém jazyce

Modelling for hydrogen diffusion in metals with traps revisited

Popis výsledku anglicky

A rigorous concept for diffusion of hydrogen is presented that allows for the role of trapping and/or hydrostatic stress. Nonlinear partial differential equations for the concentration of freely diffusing hydrogen in the lattice and for the total concentration of hydrogen both in the lattice and traps are derived. A generalized chemical diffusion coefficient can be deduced and is compared with reported relations from the literature. Simulation results are presented for different amounts of traps and their different energetic levels (depths), both for hydrogen concentration profiles and the total amount of hydrogen in the case of charging or discharging a cylindrical specimen. A significant charging/discharging asymmetry occurs for high hydrogen concentrations and high amounts of traps of sufficient depth. Comparisons of the chemical diffusion coefficient with experimental results from the literature are also presented.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BJ - Termodynamika

OECD FORD obor

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Projekt

<a href="/cs/project/GAP204%2F10%2F1784" target="_blank" >GAP204/10/1784: Modelování difúzních fázových transformací v mnohasložkových systémech s mnoha stechiometrickými fázemi</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Materialia

ISSN

1359-6454

e-ISSN

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Svazek periodika

60

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

1211-1220

Kód UT WoS článku

000301157900042

EID výsledku v databázi Scopus

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