Improvement of Hydrogen Desorption Characteristics of Eutectic Mg/Mg2NiH4 and Mg2NiH4 by In addition

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Improvement of Hydrogen Desorption Characteristics of Eutectic Mg/Mg2NiH4 and Mg2NiH4 by In addition

Popis výsledku v původním jazyce

Mg-xNi alloys are known as perspective hydrogen storage materials [1,2]. Hydrogen storage capacity and hydrogen desorption rate of binary alloys Mg-Ni are, however, still unsatisfactory and therefore, improvements are sought, e.g., by introduction of a proper catalyst [3]. As candidate elements, transition metals [4] are often used that attract bonding valence electrons and, hence, destabilize the hydrides. However, also elements with weaker bond to H than that of Mg, or even non-hydride forming elements show a beneficial effect upon the hydrogen desorption rate [5,6]. The present investigation continues our previous work [7,8]. Here we investigate the resistance of eutectic Mg/Mg2Ni against the poisoning by residual air and possible ways how to improve the hydrogen desorption kinetics of Mg2NiH4 by doping. As dopants, elements of the 13th and the 14th group were tested that do not form stable hydrides.

Název v anglickém jazyce

Improvement of Hydrogen Desorption Characteristics of Eutectic Mg/Mg2NiH4 and Mg2NiH4 by In addition

Popis výsledku anglicky

Mg-xNi alloys are known as perspective hydrogen storage materials [1,2]. Hydrogen storage capacity and hydrogen desorption rate of binary alloys Mg-Ni are, however, still unsatisfactory and therefore, improvements are sought, e.g., by introduction of a proper catalyst [3]. As candidate elements, transition metals [4] are often used that attract bonding valence electrons and, hence, destabilize the hydrides. However, also elements with weaker bond to H than that of Mg, or even non-hydride forming elements show a beneficial effect upon the hydrogen desorption rate [5,6]. The present investigation continues our previous work [7,8]. Here we investigate the resistance of eutectic Mg/Mg2Ni against the poisoning by residual air and possible ways how to improve the hydrogen desorption kinetics of Mg2NiH4 by doping. As dopants, elements of the 13th and the 14th group were tested that do not form stable hydrides.

Druh

D - Stať ve sborníku

CEP obor

JG - Hutnictví, kovové materiály

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

METAL 2012 Conference Proceedings

ISBN

978-80-87294-31-4

ISSN

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e-ISSN

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Počet stran výsledku

6

Strana od-do

1-6

Název nakladatele

TANGER Ltd. Ostrava

Místo vydání

Ostrava

Místo konání akce

Brno

Datum konání akce

23. 5. 2012

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

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