Thermally induced microstructural transformations and anti-corrosion properties of Co70Fe5Si10B15 amorphous alloy
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F18%3A00494589" target="_blank" >RIV/68081723:_____/18:00494589 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.jnoncrysol.2018.08.017" target="_blank" >http://dx.doi.org/10.1016/j.jnoncrysol.2018.08.017</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jnoncrysol.2018.08.017" target="_blank" >10.1016/j.jnoncrysol.2018.08.017</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Thermally induced microstructural transformations and anti-corrosion properties of Co70Fe5Si10B15 amorphous alloy
Popis výsledku v původním jazyce
The amorphous Co70Fe5Si10B15 alloy was studied in terms of thermal and corrosion resistance as well as thermally induced structural transformations, using several structural and thermal analysis techniques and electrochemical measurements. It was shown that the alloy is thermally stable up to around 510 °C. Anodic polarization curves of the as-prepared alloy revealed its high corrosion resistance in 0.5M NaCl, HCl and NaOH solutions. Multistep structural stabilization through the crystallization is manifested as two well defined DSC peaks corresponding to formation of fcc Co, hcp Co, Co23B6, and Co2Si phases, whose microstructural parameters were studied after thermal treatment at different temperatures in the range 25–800 °C. TEM and EDX analyses suggested the presence of minor Co-Si phases as well in the crystallized alloy and deformation twinning in the Co23B6 grains. The microstructural transformations exhibited significant influence on the magnetic moment ofnthe alloy. Kinetics of non-isothermal crystallization was studied on the bases of isoconversional principle. Determination of kinetic triplets of individual crystallization steps, based on deconvolution of the complex DSC peaks applying Fraser-Suzuki function, enabled assessment of thermal stability of the alloy and kinetic predictions at different temperatures.
Název v anglickém jazyce
Thermally induced microstructural transformations and anti-corrosion properties of Co70Fe5Si10B15 amorphous alloy
Popis výsledku anglicky
The amorphous Co70Fe5Si10B15 alloy was studied in terms of thermal and corrosion resistance as well as thermally induced structural transformations, using several structural and thermal analysis techniques and electrochemical measurements. It was shown that the alloy is thermally stable up to around 510 °C. Anodic polarization curves of the as-prepared alloy revealed its high corrosion resistance in 0.5M NaCl, HCl and NaOH solutions. Multistep structural stabilization through the crystallization is manifested as two well defined DSC peaks corresponding to formation of fcc Co, hcp Co, Co23B6, and Co2Si phases, whose microstructural parameters were studied after thermal treatment at different temperatures in the range 25–800 °C. TEM and EDX analyses suggested the presence of minor Co-Si phases as well in the crystallized alloy and deformation twinning in the Co23B6 grains. The microstructural transformations exhibited significant influence on the magnetic moment ofnthe alloy. Kinetics of non-isothermal crystallization was studied on the bases of isoconversional principle. Determination of kinetic triplets of individual crystallization steps, based on deconvolution of the complex DSC peaks applying Fraser-Suzuki function, enabled assessment of thermal stability of the alloy and kinetic predictions at different temperatures.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
<a href="/cs/project/LQ1601" target="_blank" >LQ1601: CEITEC 2020</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2018
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Non-Crystalline Solids
ISSN
0022-3093
e-ISSN
—
Svazek periodika
500
Číslo periodika v rámci svazku
NOV
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
10
Strana od-do
326-335
Kód UT WoS článku
000447096600042
EID výsledku v databázi Scopus
2-s2.0-85053405509