Structure refinement and superspace description of the system Bi2(n + 2)MonO6(n + 1) (n = 3, 4, 5 and 6)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00384844" target="_blank" >RIV/68378271:_____/12:00384844 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1107/S0108768112017478" target="_blank" >http://dx.doi.org/10.1107/S0108768112017478</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1107/S0108768112017478" target="_blank" >10.1107/S0108768112017478</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Structure refinement and superspace description of the system Bi2(n + 2)MonO6(n + 1) (n = 3, 4, 5 and 6)

Popis výsledku v původním jazyce

The system Bi2(n + 2)MonO6(n + 1) is described within the superspace formalism. Two superspace models are proposed for the different members of this family, depending on the parity of the parameter n. The superspace model for the odd members is constructed through the embedding of the cationic distribution of the member with n = 3, and the modification of a superspace model previously proposed for the compound Bi2MoO6. However, this model cannot be applied to the even members of the family. Performing the appropriate transformations, a suitable superspace model for the even members is obtained. The atomic structure of the different compounds of the family have been refined through the Rietveld method combining synchrotron X-ray and neutron powder diffraction data.

Název v anglickém jazyce

Structure refinement and superspace description of the system Bi2(n + 2)MonO6(n + 1) (n = 3, 4, 5 and 6)

Popis výsledku anglicky

The system Bi2(n + 2)MonO6(n + 1) is described within the superspace formalism. Two superspace models are proposed for the different members of this family, depending on the parity of the parameter n. The superspace model for the odd members is constructed through the embedding of the cationic distribution of the member with n = 3, and the modification of a superspace model previously proposed for the compound Bi2MoO6. However, this model cannot be applied to the even members of the family. Performing the appropriate transformations, a suitable superspace model for the even members is obtained. The atomic structure of the different compounds of the family have been refined through the Rietveld method combining synchrotron X-ray and neutron powder diffraction data.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Crystallographica section B - Structural Science

ISSN

0108-7681

e-ISSN

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Svazek periodika

68

Číslo periodika v rámci svazku

Part 4

Stát vydavatele periodika

DK - Dánské království

Počet stran výsledku

18

Strana od-do

323-340

Kód UT WoS článku

000306570600001

EID výsledku v databázi Scopus

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