Polynuclear oxovanadium(IV) Schiff base complex [VOL2]n (L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine): synthesis, characterization, crystal structure, catalytic properties and thermal decomposition into V2O5 nano-particles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00391618" target="_blank" >RIV/68378271:_____/13:00391618 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.inoche.2012.10.029" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2012.10.029</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.inoche.2012.10.029" target="_blank" >10.1016/j.inoche.2012.10.029</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Polynuclear oxovanadium(IV) Schiff base complex [VOL2]n (L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine): synthesis, characterization, crystal structure, catalytic properties and thermal decomposition into V2O5 nano-particles

Popis výsledku v původním jazyce

Polynuclear oxovanadium(IV) Schiff base complex was synthesized and characterized by elemental analysis and FT-IR spectroscopy. Its crystal structure has been determined by single crystal X-ray diffraction. The complex has two symmetry independent vanadium centers located on a two-fold axis.Both centers have a distorted octahedral N2O4 coordination sphere. Two Schiff base ligands coordinate to the vanadium center each via one nitrogen and one oxygen atom. The remaining two apices of the octahedron are occupied by oxygen shared by the neighboring vanadium atoms, giving rise to 1D coordination polymer [VOL2]n with the interatomic VV distance 3.7670(6) A. This complex is used as a catalyst for the epoxidation of the cyclooctene.

Název v anglickém jazyce

Polynuclear oxovanadium(IV) Schiff base complex [VOL2]n (L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine): synthesis, characterization, crystal structure, catalytic properties and thermal decomposition into V2O5 nano-particles

Popis výsledku anglicky

Polynuclear oxovanadium(IV) Schiff base complex was synthesized and characterized by elemental analysis and FT-IR spectroscopy. Its crystal structure has been determined by single crystal X-ray diffraction. The complex has two symmetry independent vanadium centers located on a two-fold axis.Both centers have a distorted octahedral N2O4 coordination sphere. Two Schiff base ligands coordinate to the vanadium center each via one nitrogen and one oxygen atom. The remaining two apices of the octahedron are occupied by oxygen shared by the neighboring vanadium atoms, giving rise to 1D coordination polymer [VOL2]n with the interatomic VV distance 3.7670(6) A. This complex is used as a catalyst for the epoxidation of the cyclooctene.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganic Chemistry Communications

ISSN

1387-7003

e-ISSN

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Svazek periodika

27

Číslo periodika v rámci svazku

JAN

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

6

Strana od-do

82-87

Kód UT WoS článku

000314618700020

EID výsledku v databázi Scopus

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