A novel amido?pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00398666" target="_blank" >RIV/68378271:_____/13:00398666 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1107/S0108270113000814" target="_blank" >http://dx.doi.org/10.1107/S0108270113000814</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1107/S0108270113000814" target="_blank" >10.1107/S0108270113000814</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A novel amido?pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Popis výsledku v původním jazyce

The title complex is the first example of a bis-chelate amido-pyrophosphate (pyrophosphoramide) complex containing an O[P(O)(NH)2]2 fragment. Its asymmetric unit contains half of the complex dication, one chloride anion and one water molecule. The MnII atom, located on an inversion centre, is octahedrally coordinated. Structural features, such as the P O bond lengths and the planarity of the chelate ring, are compared with those of previously reported complexes with six-membered chelates involving the fragments C(O)NHP(O), (X)NP(O) [X = C(O), C(S), S(O)2 and P(O)] and O[P(O)(N)2]2. The extended structure of the title complex involves a linear aggregate mediated by hydrogen bonds, in which the chloride anion is an acceptor in two additional O?H...Cl hydrogen bonds.

Název v anglickém jazyce

A novel amido?pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Popis výsledku anglicky

The title complex is the first example of a bis-chelate amido-pyrophosphate (pyrophosphoramide) complex containing an O[P(O)(NH)2]2 fragment. Its asymmetric unit contains half of the complex dication, one chloride anion and one water molecule. The MnII atom, located on an inversion centre, is octahedrally coordinated. Structural features, such as the P O bond lengths and the planarity of the chelate ring, are compared with those of previously reported complexes with six-membered chelates involving the fragments C(O)NHP(O), (X)NP(O) [X = C(O), C(S), S(O)2 and P(O)] and O[P(O)(N)2]2. The extended structure of the title complex involves a linear aggregate mediated by hydrogen bonds, in which the chloride anion is an acceptor in two additional O?H...Cl hydrogen bonds.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Crystallographica. C - Crystal Structure Communications

ISSN

0108-2701

e-ISSN

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Svazek periodika

69

Číslo periodika v rámci svazku

Mar

Stát vydavatele periodika

DK - Dánské království

Počet stran výsledku

4

Strana od-do

225-228

Kód UT WoS článku

000315648600005

EID výsledku v databázi Scopus

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