Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-?N1)bis(5,5'-dimethyl-2,2'-bipyridine-?2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00421119" target="_blank" >RIV/68378271:_____/13:00421119 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1107/S0108270113027091" target="_blank" >http://dx.doi.org/10.1107/S0108270113027091</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S0108270113027091" target="_blank" >10.1107/S0108270113027091</a>

Jazyk výsledku
angličtina
Název v původním jazyce
Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-?N1)bis(5,5'-dimethyl-2,2'-bipyridine-?2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions
Popis výsledku v původním jazyce
The title compounds are isomorphous and consist of [Cu{N(CN)2}(mbpy)2]+ cations (mbpy is 5,50-dimethyl-2,20-bipyridine) and BF4 or ClO4 anions. The CuII cations in both structures are five-coordinated in distorted trigonal bipyramidal environments by four N atoms of two mbpy ligands and one N atom of the dicyanamide anion, which is coordinated in a monodentate manner in the equatorial plane. The work presents detailed crystallographic structures of both compounds and their comparison.
Název v anglickém jazyce
Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-?N1)bis(5,5'-dimethyl-2,2'-bipyridine-?2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions
Popis výsledku anglicky
The title compounds are isomorphous and consist of [Cu{N(CN)2}(mbpy)2]+ cations (mbpy is 5,50-dimethyl-2,20-bipyridine) and BF4 or ClO4 anions. The CuII cations in both structures are five-coordinated in distorted trigonal bipyramidal environments by four N atoms of two mbpy ligands and one N atom of the dicyanamide anion, which is coordinated in a monodentate manner in the equatorial plane. The work presents detailed crystallographic structures of both compounds and their comparison.

Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
BM - Fyzika pevných látek a magnetismus
OECD FORD obor
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Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění
2013
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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