Shape Selective Photoinduced Electrochemical Behaviour of Thin ZnO Layers Prepared by Surfatron.
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00453099" target="_blank" >RIV/68378271:_____/15:00453099 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/67985858:_____/15:00453099
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.tsf.2015.11.003" target="_blank" >http://dx.doi.org/10.1016/j.tsf.2015.11.003</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tsf.2015.11.003" target="_blank" >10.1016/j.tsf.2015.11.003</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Shape Selective Photoinduced Electrochemical Behaviour of Thin ZnO Layers Prepared by Surfatron.
Popis výsledku v původním jazyce
The rutile effect on structural and photo-electrochemical properties and photo-induced activity were studied. Thin TiO2 layers were prepared by the sol-gel method using a reverse micelles system as a molecular template and deposited on the conductive ITOsubstrate by a dip-coating technique. Pure anatase or mixed anatase/rutile phase were obtained during the calcination step as a result of the selected temperature. The crystallographic structure was determined by Raman spectroscopy and XRD analysis. Thepositive influence of the presence of rutile particles in the thin layer on the photo-induced properties was verified. It was found that the mixed crystallographic phase of anatase and rutile can exhibit much higher photo-induced activity than pure anatase or the pure rutile form. The reason for this is that the excited electrons can easily transfer from the anatase surface states to rutile as well as from the anatase conduction band to rutile, which improves the electron-transfer rate.
Název v anglickém jazyce
Shape Selective Photoinduced Electrochemical Behaviour of Thin ZnO Layers Prepared by Surfatron.
Popis výsledku anglicky
The rutile effect on structural and photo-electrochemical properties and photo-induced activity were studied. Thin TiO2 layers were prepared by the sol-gel method using a reverse micelles system as a molecular template and deposited on the conductive ITOsubstrate by a dip-coating technique. Pure anatase or mixed anatase/rutile phase were obtained during the calcination step as a result of the selected temperature. The crystallographic structure was determined by Raman spectroscopy and XRD analysis. Thepositive influence of the presence of rutile particles in the thin layer on the photo-induced properties was verified. It was found that the mixed crystallographic phase of anatase and rutile can exhibit much higher photo-induced activity than pure anatase or the pure rutile form. The reason for this is that the excited electrons can easily transfer from the anatase surface states to rutile as well as from the anatase conduction band to rutile, which improves the electron-transfer rate.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
BL - Fyzika plasmatu a výboje v plynech
OECD FORD obor
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Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2015
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Thin Solid Films
ISSN
0040-6090
e-ISSN
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Svazek periodika
597
Číslo periodika v rámci svazku
DEC 31
Stát vydavatele periodika
CH - Švýcarská konfederace
Počet stran výsledku
9
Strana od-do
131-139
Kód UT WoS článku
000366647000021
EID výsledku v databázi Scopus
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