A novel trinuclear copper(II) complex containing a symmetric tetradentate N2O2 Schiff base ligand: synthesis, characterization, crystal structure and its usage as a new precursor for the preparation of CuO particles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473782" target="_blank" >RIV/68378271:_____/17:00473782 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.poly.2016.09.029" target="_blank" >http://dx.doi.org/10.1016/j.poly.2016.09.029</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2016.09.029" target="_blank" >10.1016/j.poly.2016.09.029</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A novel trinuclear copper(II) complex containing a symmetric tetradentate N2O2 Schiff base ligand: synthesis, characterization, crystal structure and its usage as a new precursor for the preparation of CuO particles

Popis výsledku v původním jazyce

A novel linear centrosymmetric trinuclear copper(II) Schiff base complex with the chemical formula [{Cu (mu-L)(H2O)(mu-NO3)}(2)Cu]center dot H2O, where L = N,N'-bis(2-hydroxy-4-methoxybenzophenone)-2,2-dimethyl-1,3-propanediamine, was synthesized and characterized by elemental analyses, FT-IR spectroscopy, TG-TA and X-ray crystallography. Single X-ray diffraction analysis revealed four mu-phenoxido- and two mu-NO3- bridges in the complex. The equatorial plane of the three linearly arranged copper(II) atoms is formed by oxygen and nitrogen atoms of two anionic tetradentate Schiff base ligands, each of them coordinated to one of the terminal copper(II) ions. The central copper(II) ion is located in an inversion centre and bonded to four pt-oxygen atoms of the same ligand. Thermogravimetric analysis of the complex revealed its thermal stability and decomposition pattern.

Název v anglickém jazyce

A novel trinuclear copper(II) complex containing a symmetric tetradentate N2O2 Schiff base ligand: synthesis, characterization, crystal structure and its usage as a new precursor for the preparation of CuO particles

Popis výsledku anglicky

A novel linear centrosymmetric trinuclear copper(II) Schiff base complex with the chemical formula [{Cu (mu-L)(H2O)(mu-NO3)}(2)Cu]center dot H2O, where L = N,N'-bis(2-hydroxy-4-methoxybenzophenone)-2,2-dimethyl-1,3-propanediamine, was synthesized and characterized by elemental analyses, FT-IR spectroscopy, TG-TA and X-ray crystallography. Single X-ray diffraction analysis revealed four mu-phenoxido- and two mu-NO3- bridges in the complex. The equatorial plane of the three linearly arranged copper(II) atoms is formed by oxygen and nitrogen atoms of two anionic tetradentate Schiff base ligands, each of them coordinated to one of the terminal copper(II) ions. The central copper(II) ion is located in an inversion centre and bonded to four pt-oxygen atoms of the same ligand. Thermogravimetric analysis of the complex revealed its thermal stability and decomposition pattern.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polyhedron

ISSN

0277-5387

e-ISSN

—

Svazek periodika

121

Číslo periodika v rámci svazku

Jan

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

4

Strana od-do

9-12

Kód UT WoS článku

000390626200002

EID výsledku v databázi Scopus

2-s2.0-84992533006