Six-coordinate oxo-vanadium(V) dimer complex with methoxy bridging: synthesis, crystal structure, biological activity and molecular docking

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473827" target="_blank" >RIV/68378271:_____/17:00473827 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.inoche.2016.11.015" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2016.11.015</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.inoche.2016.11.015" target="_blank" >10.1016/j.inoche.2016.11.015</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Six-coordinate oxo-vanadium(V) dimer complex with methoxy bridging: synthesis, crystal structure, biological activity and molecular docking

Popis výsledku v původním jazyce

A diketone-based tridentate Schiff base, 3-[(2-hydroxyphenyl)amino]-1,3-diphenylprop-2-en-1-one (H2L), and its oxo-vanadium(V) dimer complex, [VO(L)(OMe)]2, were synthesized and characterized using spectroscopic and physicochemical techniques. Single crystal X-ray diffraction indicated that the Schiff base ligand in its deprotonated form was found to bind to the V(V) ion through the azomethine nitrogen, amine and phenolic oxygens in a distorted octahedral geometry. The other positions around the V(V) center were occupied by an oxido group and two oxygens from methoxido ligands. Antimicrobial studies showed that the synthesized complex indicated significant antimicrobial activities against Escherichia coli (ATCC 25922) and Staphylococcus aureus (ATCC 33591 and 29213) bacteria while no antibacterial activity was observed for the ligand alone.

Název v anglickém jazyce

Six-coordinate oxo-vanadium(V) dimer complex with methoxy bridging: synthesis, crystal structure, biological activity and molecular docking

Popis výsledku anglicky

A diketone-based tridentate Schiff base, 3-[(2-hydroxyphenyl)amino]-1,3-diphenylprop-2-en-1-one (H2L), and its oxo-vanadium(V) dimer complex, [VO(L)(OMe)]2, were synthesized and characterized using spectroscopic and physicochemical techniques. Single crystal X-ray diffraction indicated that the Schiff base ligand in its deprotonated form was found to bind to the V(V) ion through the azomethine nitrogen, amine and phenolic oxygens in a distorted octahedral geometry. The other positions around the V(V) center were occupied by an oxido group and two oxygens from methoxido ligands. Antimicrobial studies showed that the synthesized complex indicated significant antimicrobial activities against Escherichia coli (ATCC 25922) and Staphylococcus aureus (ATCC 33591 and 29213) bacteria while no antibacterial activity was observed for the ligand alone.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganic Chemistry Communications

ISSN

1387-7003

e-ISSN

—

Svazek periodika

76

Číslo periodika v rámci svazku

Feb

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

4

Strana od-do

1-4

Kód UT WoS článku

000395608100001

EID výsledku v databázi Scopus

2-s2.0-85007369849