Electron self-trapped at molybdenum complex in lead molybdate: An EPRand TSL comparative study

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00483154" target="_blank" >RIV/68378271:_____/17:00483154 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.jlumin.2017.07.066" target="_blank" >http://dx.doi.org/10.1016/j.jlumin.2017.07.066</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jlumin.2017.07.066" target="_blank" >10.1016/j.jlumin.2017.07.066</a>

Jazyk výsledku
angličtina
Název v původním jazyce
Electron self-trapped at molybdenum complex in lead molybdate: An EPRand TSL comparative study
Popis výsledku v původním jazyce
Single crystals of PbMoO4 were studied by means of light-induced EPR and wavelength resolved TSL. The work is focused on the electron self-trapped at the (MoO4)2- complex. Detailed analysis of the EPR spectra of this complex allowed to determine a set of spin-Hamiltonian parameters further used in calculations performed in terms of crystal field and LCAO-MO theories. They have shown a significant overlap of the Mo ligand lead orbitals. Trap depth and frequency factor of the electron trap, Et = 0.05 eV, and f0 = 104 s−1, have been determined in correlation with TSL.
Název v anglickém jazyce
Electron self-trapped at molybdenum complex in lead molybdate: An EPRand TSL comparative study
Popis výsledku anglicky
Single crystals of PbMoO4 were studied by means of light-induced EPR and wavelength resolved TSL. The work is focused on the electron self-trapped at the (MoO4)2- complex. Detailed analysis of the EPR spectra of this complex allowed to determine a set of spin-Hamiltonian parameters further used in calculations performed in terms of crystal field and LCAO-MO theories. They have shown a significant overlap of the Mo ligand lead orbitals. Trap depth and frequency factor of the electron trap, Et = 0.05 eV, and f0 = 104 s−1, have been determined in correlation with TSL.

Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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