Chiral Surface from achiral ingredients: modification of Cu(110) with phthalic acid

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00521271" target="_blank" >RIV/68378271:_____/19:00521271 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1021/acs.jpcc.9b00637" target="_blank" >https://doi.org/10.1021/acs.jpcc.9b00637</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acs.jpcc.9b00637" target="_blank" >10.1021/acs.jpcc.9b00637</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Chiral Surface from achiral ingredients: modification of Cu(110) with phthalic acid

Popis výsledku v původním jazyce

The adsorption of dicarboxylic acids is a classical model approach for understanding molecular recognition at surfaces. The interaction of achiral phthalic acid with an achiral Cu(110) surface has been investigated in ultrahigh vacuum by means of scanning tunneling microscopy, low-energy electron diffraction, X-ray photoelectron spectroscopy, reflection absorption infrared spectroscopy, temperature-programmed desorption, and density functional theory. Different ordered domains at a length scale of several tens of nanometers are observed, of which three are enantiomorphous and therefore appear in two mirror-symmetric forms. Theoretical considerations suggest that spontaneous mirror-symmetry breaking occurs at the single-molecular level, in which the surface becomes also chirally distorted.

Název v anglickém jazyce

Chiral Surface from achiral ingredients: modification of Cu(110) with phthalic acid

Popis výsledku anglicky

The adsorption of dicarboxylic acids is a classical model approach for understanding molecular recognition at surfaces. The interaction of achiral phthalic acid with an achiral Cu(110) surface has been investigated in ultrahigh vacuum by means of scanning tunneling microscopy, low-energy electron diffraction, X-ray photoelectron spectroscopy, reflection absorption infrared spectroscopy, temperature-programmed desorption, and density functional theory. Different ordered domains at a length scale of several tens of nanometers are observed, of which three are enantiomorphous and therefore appear in two mirror-symmetric forms. Theoretical considerations suggest that spontaneous mirror-symmetry breaking occurs at the single-molecular level, in which the surface becomes also chirally distorted.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physical Chemistry C

ISSN

1932-7447

e-ISSN

—

Svazek periodika

123

Číslo periodika v rámci svazku

14

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

9121-9127

Kód UT WoS článku

000464768600071

EID výsledku v databázi Scopus

2-s2.0-85063439472