Thermal analysis of cesium hafnium chloride using DSC–TG under vacuum, nitrogen atmosphere, and in enclosed system

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00533015" target="_blank" >RIV/68378271:_____/20:00533015 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68407700:21340/20:00335787

Výsledek na webu

<a href="https://doi.org/10.1007/s10973-019-09087-7" target="_blank" >https://doi.org/10.1007/s10973-019-09087-7</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10973-019-09087-7" target="_blank" >10.1007/s10973-019-09087-7</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Thermal analysis of cesium hafnium chloride using DSC–TG under vacuum, nitrogen atmosphere, and in enclosed system

Popis výsledku v původním jazyce

This paper reports on the preparation of undoped Cs2HfCl6 and study of its thermal properties. The Cs2HfCl6 material was successfully synthesized from a cesium chloride and a hafnium chloride mixed together in stoichiometric ratio. The presence of only one crystalline phase of the Cs2HfCl6 in the material was confirmed by the X-ray diffraction analysis. The simultaneous DSC–TG thermal analysis of the synthesized material under nitrogen atmosphere, vacuum, and in enclosed system was performed. The Cs2HfCl6 decomposition and melting of CsCl–Cs2HfCl6 mixture under nitrogen and vacuum were observed. On the contrary, the DSC measurement of the cesium hafnium chloride in enclosed system showed only one endothermic peak related to the congruent melting point. Furthermore, the repeated DSC–TG measurements to investigate the materials’ stability in enclosed system were carried out as well.n

Název v anglickém jazyce

Thermal analysis of cesium hafnium chloride using DSC–TG under vacuum, nitrogen atmosphere, and in enclosed system

Popis výsledku anglicky

This paper reports on the preparation of undoped Cs2HfCl6 and study of its thermal properties. The Cs2HfCl6 material was successfully synthesized from a cesium chloride and a hafnium chloride mixed together in stoichiometric ratio. The presence of only one crystalline phase of the Cs2HfCl6 in the material was confirmed by the X-ray diffraction analysis. The simultaneous DSC–TG thermal analysis of the synthesized material under nitrogen atmosphere, vacuum, and in enclosed system was performed. The Cs2HfCl6 decomposition and melting of CsCl–Cs2HfCl6 mixture under nitrogen and vacuum were observed. On the contrary, the DSC measurement of the cesium hafnium chloride in enclosed system showed only one endothermic peak related to the congruent melting point. Furthermore, the repeated DSC–TG measurements to investigate the materials’ stability in enclosed system were carried out as well.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

—

Svazek periodika

141

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

HU - Maďarsko

Počet stran výsledku

7

Strana od-do

1101-1107

Kód UT WoS článku

000499820900004

EID výsledku v databázi Scopus

2-s2.0-85076089834